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Because of its large density-of-states and the 2{pi} Berry phase near its low-energy band-contact points, neutral bilayer graphene (BLG) at zero magnetic field (B) is susceptible to chiral-symmetry breaking, leading to a variety of gapped spontaneous quantum Hall states distinguished by valley and spin-dependent quantized Hall conductivities. Among these, the layer antiferromagnetic state, which has quantum valley Hall (QVH) effects of opposite sign for opposite spins, appears to be the thermodynamic ground state. Though other gapped states have not been observed experimentally at B=0, they can be explored by exploiting their adiabatic connection to quantum Hall states with the same total Hall conductivity {sigma}H. In this paper, by using a magnetic field to select filling factor { u}=2 states with {sigma}H=2e^2/h, we demonstrate the presence of a quantum anomalous Hall (QAH) state for the majority spin, and a Kekule state with spontaneous valley coherence and a quantum valley Hall state for the minority spin in BLG. By providing the first spectroscopic mapping of spontaneous Hall states at { u}=2, our results shed further light on the rich set of competing ordered states in BLG.
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Bilayer graphene is a highly promising material for electronic and optoelectronic applications since it is supporting massive Dirac fermions with a tuneable band gap. However, no consistent picture of the gaps effect on the optical and transport beha