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We report on the focusing and guiding of the van der Waals complex formed between benzonitrile molecules (C$_6$H$_5$CN) and argon atoms in a cold molecular beam using an ac electric quadrupole guide. The distribution of quantum states in the guided beam is non-thermal, because the transmission efficiency depends on the state-dependent effective dipole moment in the applied electric fields. At a specific ac frequency, however, the excitation spectrum can be described by a thermal distribution at a rotational temperature of 0.8 K. From the observed transmission characteristics and a combination of trajectory and Stark-energy calculations we conclude that the permanent electric dipole moment of benzonitrile remains unchanged upon the attachment of the argon atom to within pm5%. By exploiting the different dipole-moment-to-mass (mu/m) ratios of the complex and the benzonitrile monomer, transmission can be selectively suppressed for or, in the limit of 0 K rotational temperature, restricted to the complex.
The non-local van der Waals density functional (vdW-DF) has had tremendous success since its inception in 2004 due to its constraint-based formalism that is rigorously derived from a many-body starting point. However, while vdW-DF can describe bindin
We have focused and decelerated benzonitrile (C$_7$H$_5$N) molecules from a molecular beam, using an array of time-varying inhomogeneous electric fields in alternating gradient configuration. Benzonitrile is prototypical for large asymmetric top mole
We report on the direct measurement in real space of the effect of the van der Waals forces between individual Rydberg atoms on their external degrees of freedom. Clusters of Rydberg atoms with inter-particle distances of around 5 {mu}m are created b
In inhomogeneous dielectric media the divergence of the electromagnetic stress is related to the gradients of varepsilon and mu, which is a consequence of Maxwells equations. Investigating spherically symmetric media we show that this seemingly unive
We study the repulsive van der Waals interaction of cold rubidium $70S_{1/2}$ Rydberg atoms by analysis of time-delayed pair correlation functions. After excitation, Rydberg atoms are allowed to accelerate under the influence of the van der Waals for