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Momentum dependence of the excitons in pentacene

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 نشر من قبل Friedrich Roth
 تاريخ النشر 2012
  مجال البحث فيزياء
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We have carried out electron energy-loss investigations of the lowest singlet excitons in pentacene at 20 K. Our studies allow to determine the full exciton band structure in the a*,b* reciprocal lattice plane. The lowest singlet exciton can move coherently within this plane, and the resulting exciton dispersion is highly anisotropic. The analysis of the energetically following (satellite) features indicates a strong admixture of charge transfer excitations to the exciton wave function.

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