اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدRotational and Translational Phonon Modes in Glasses Composed of Ellipsoidal Particles
162
0
0.0
(
0
)
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
The effects of particle shape on the vibrational properties of colloidal glasses are studied experimentally. Ellipsoidal glasses are created by stretching polystyrene spheres to different aspect ratios and then suspending the resulting ellipsoidal particles in water at high packing fraction. By measuring displacement correlations between particles, we extract vibrational properties of the corresponding shadow ellipsoidal glass with the same geometric configuration and interactions as the source suspension but without damping. Low frequency modes in glasses composed of ellipsoidal particles with major/minor axis aspect ratios $sim$1.1 are observed to have predominantly rotational character. By contrast, low frequency modes in glasses of ellipsoidal particles with larger aspect ratios ($sim$3.0) exhibit a mix of rotational and translational character. All glass samples were characterized by a distribution of particles with different aspect ratios. Interestingly, even within the same sample it was found that small-aspect-ratio particles participate relatively more in rotational modes, while large-aspect-ratio particles tend to participate relatively more in translational modes.
قيم البحث
اقرأ أيضاً
We numerically study the evolution of the vibrational density of states $D(omega)$ of zero-temperature glasses when their kinetic stability is varied over an extremely broad range, ranging from poorly annealed glasses obtained by instantaneous quench
es from above the onset temperature, to ultrastable glasses obtained by quenching systems thermalised below the experimental glass temperature. The low-frequency part of the density of states splits between extended and quasi-localized modes. Extended modes exhibit a boson peak crossing over to Debye behaviour ($D(omega) sim omega^2$) at low-frequency, with a strong correlation between the two regimes. Quasi-localized modes instead obey $D(omega) sim omega^4$, irrespective of the glass stability. However, the prefactor of this quartic law becomes smaller in more stable glasses, and the corresponding modes become more localized and sparser. Our work is the first numerical observation of quasi-localized modes in a regime relevant to experiments, and it establishes a direct connection between glass stability and soft vibrational motion in amorphous solids.
We compute the dielectric response of glasses starting from a microscopic system-bath Hamiltonian of the Zwanzig-Caldeira-Leggett type and using an ansatz from kinetic theory for the memory function in the resulting Generalized Langevin Equation. The
resulting framework requires the knowledge of the vibrational density of states (DOS) as input, that we take from numerical evaluation of a marginally-stable harmonic disordered lattice, featuring a strong boson peak (excess of soft modes over Debye $simomega_{p}^{2}$ law). The dielectric function calculated based on this ansatz is compared with experimental data for the paradigmatic case of glycerol at $Tlesssim T_{g}$. Good agreement is found for both the reactive (real part) of the response and for the $alpha$-relaxation peak in the imaginary part, with a significant improvement over earlier theoretical approaches, especially in the reactive modulus. On the low-frequency side of the $alpha$-peak, the fitting supports the presence of $sim omega_{p}^{4}$ modes at vanishing eigenfrequency as recently shown in [Phys. Rev. Lett. 117, 035501 (2016)]. $alpha$-wing asymmetry and stretched-exponential behaviour are recovered by our framework, which shows that these features are, to a large extent, caused by the soft boson-peak modes in the DOS.
We performed rheological measurements of the typical deep eutectic solvents (DESs) glyceline, ethaline, and reline in a very broad temperature and dynamic range, extending from the low-viscosity to the high-viscosity supercooled-liquid regime. We fin
d that the mechanical compliance spectra can be well described by the random free-energy barrier hopping model, while the dielectric spectra on the same materials involve significant contributions arising from reorientational dynamics. The temperature-dependent viscosity and structural relaxation time, revealing non-Arrhenius behavior typical for glassy freezing, are compared to the ionic dc conductivity and relaxation times determined by broadband dielectric spectroscopy. For glyceline and ethaline we find essentially identical temperature dependences for all dynamic quantities. These findings point to a close coupling of the ionic and molecular translational and reorientational motions in these systems. However, for reline the ionic charge transport appears decoupled from the structural and reorientational dynamics, following a fractional Walden rule. Especially, at low temperatures the ionic conductivity in this DES is enhanced by about one decade compared to expectations based on the temperature dependence of the viscosity. The results for all three DESs can be understood without invoking a revolving-door mechanism previously considered as a possible charge-transport mechanism in DESs.
We numerically investigate the mechanical properties of static packings of ellipsoidal particles in 2D and 3D over a range of aspect ratio and compression $Delta phi$. While amorphous packings of spherical particles at jamming onset ($Delta phi=0$) a
re isostatic and possess the minimum contact number $z_{rm iso}$ required for them to be collectively jammed, amorphous packings of ellipsoidal particles generally possess fewer contacts than expected for collective jamming ($z < z_{rm iso}$) from naive counting arguments, which assume that all contacts give rise to linearly independent constraints on interparticle separations. To understand this behavior, we decompose the dynamical matrix $M=H-S$ for static packings of ellipsoidal particles into two important components: the stiffness $H$ and stress $S$ matrices. We find that the stiffness matrix possesses $N(z_{rm iso} - z)$ eigenmodes ${hat e}_0$ with zero eigenvalues even at finite compression, where $N$ is the number of particles. In addition, these modes ${hat e}_0$ are nearly eigenvectors of the dynamical matrix with eigenvalues that scale as $Delta phi$, and thus finite compression stabilizes packings of ellipsoidal particles. At jamming onset, the harmonic response of static packings of ellipsoidal particles vanishes, and the total potential energy scales as $delta^4$ for perturbations by amplitude $delta$ along these `quartic modes, ${hat e}_0$. These findings illustrate the significant differences between static packings of spherical and ellipsoidal particles.
Active glassy matter has recently emerged as a novel class of non-equilibrium soft matter, combining energy-driven, active particle movement with dense and disordered glass-like behavior. Here we review the state-of-the-art in this field from an expe
rimental, numerical, and theoretical perspective. We consider both non-living and living active glassy systems, and discuss how several hallmarks of glassy dynamics (dynamical slowdown, fragility, dynamical heterogeneity, violation of the Stokes-Einstein relation, and aging) are manifested in such materials. We start by reviewing the recent experimental evidence in this area of research, followed by an overview of the main numerical simulation studies and physical theories of active glassy matter. We conclude by outlining several open questions and possible directions for future work.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
