اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدTheory of Inelastic Tunneling Current-Driven Motions of Single Adsorbates (Review Article)
48
0
0.0
(
0
)
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
The theory of inelastic electron tunneling spectroscopy (IETS) and motions of single adsorbed atoms and molecules on metal surfaces induced by vibrational excitation with a scanning tunneling microscope (STM) is reviewed. The theory of STM-IETS is described using the adsorbate-induced resonance model. Elementary processes of how an adsorbate overcomes the potential barrier along the reaction coordinate (RC) by inelastic tunneling current are described with a focus on direct excitation of the RC mode by coherent and incoherent vibrational ladder climbing and an indirect one through anharmonic coupling to a mode excited by tunneling electrons. Action spectroscopy of single molecule motions is also discussed. The latter allows a direct access to the vibrational density of states, which can not be otherwise observed in the STM-IETS because of a competition between the elastic and inelastic tunneling currents.
قيم البحث
اقرأ أيضاً
The role of the tip in inelastic electron tunneling spectroscopy (IETS) performed with scanning tunneling microscopes (STM) is theoretically addressed via first-principles simulations of vibrational spectra of single carbon monoxide (CO) molecules ad
sorbed on Cu(111). We show how chemically functionalized STM tips modify the IETS intensity corresponding to adsorbate modes on the sample side. The underlying propensity rules are explained using symmetry considerations for both the vibrational modes and the molecular orbitals of the tip and sample. This suggests that single-molecule IETS can be optimized by selecting the appropriate tip orbital symmetry.
Two basic physical models, a two-level system and a harmonic oscillator, are realized on the mesoscopic scale as coupled qubit and resonator. The realistic system includes moreover the electronics for controlling the distance between the qubit energy
levels and their populations and to read out the resonators state, as well as the unavoidable dissipative environment. Such rich system is interesting both for the study of fundamental quantum phenomena on the mesoscopic scale and as a promising system for future electronic devices. We present recent results for the driven superconducting qubit-resonator system, where the resonator can be realized as an LC circuit or a nanomechanical resonator. Most of the results can be described by the semiclassical theory, where a qubit is treated as a quantum two-level system coupled to the classical driving field and the classical resonator. Application of this theory allows to describe many phenomena for the single and two coupled superconducting qubits, among which are the following: the equilibrium-state and weak-driving spectroscopy, Sisyphus damping and amplification, Landau-Zener-Stuckelberg interferometry, the multiphoton transitions of both direct and ladder- type character, and creation of the inverse population for lasing.
We study pentanedithiol molecular junctions formed by means of the break-junction technique with a scanning tunneling microscope at low temperatures. Using inelastic electron tunneling spectroscopy and first-principles calculations, the response of t
he junction to elastic deformation is examined. We show that this procedure makes a detailed characterization of the molecular junction possible. In particular, our results indicate that tunneling takes place through just a single molecule.
The controlled and accurate emission of coherent electronic wave packets is of prime importance for future applications of nano-scale electronics. Here we present a theoretical and experimental analysis of the finite-frequency noise spectrum of a per
iodically driven single electron emitter. The electron source consists of a mesoscopic capacitor that emits single electrons and holes into a chiral edge state of a quantum Hall sample. We compare experimental results with two complementary theoretical descriptions: On one hand, the Floquet scattering theory which leads to accurate numerical results for the noise spectrum under all relevant operating conditions. On the other hand, a semi-classical model which enables us to develop an analytic description of the main sources of noise when the emitter is operated under optimal conditions. We find excellent agreement between experiment and theory. Importantly, the noise spectrum provides us with an accurate description and characterization of the mesoscopic capacitor when operated as a periodic single electron emitter.
We consider tunneling transport through a Mn$_{12}$ molecular magnet using spin density functional theory. A tractable methodology for constructing many-body wavefunctions from Kohn-Sham orbitals allows for the determination of spin-dependent matrix
elements for use in transport calculations. The tunneling conductance at finite bias is characterized by peaks representing transitions between spin multiplets, separated by an energy on the order of the magnetic anisotropy. The energy splitting of the spin multiplets and the spatial part of their many-body wave functions, describing the orbital degrees of freedom of the excess charge, strongly affect the electronic transport, and can lead to negative differential conductance.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
