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The newest homologous series of superconducting As-pnictides, LiFeAs (Li111) and NaFeAs (Na111) have been synthesized and investigated. Both crystallize with the layered tetragonal anti-PbFCl-type structure in P4/nmm space group. Polycrystalline samples and single-crystals of Li111 and Na111 display superconducting transitions at ~ 18 K and 12-25 K, respectively. No magnetic order has been found in either compound, although a weak magnetic background is clearly in evidence. The origin of the carriers and the stoichiometric compositions of Li111 and Na111 were explored.
Results of resonant inelastic X-ray scattering (RIXS) measurements at Fe L-edges and electronic structure calculations of LiFeAs and NaFeAs are presented. Both experiment and theory show that in the vicinity of the Fermi energy, the density of states
The lithium ions in Lithium iron arsenide phases with compositions close to LiFeAs have been located using powder neutron diffraction. These phases exhibit superconductivity at temperatures at least as high as 16 K demonstrating that superconductivit
Rare-earth nickelates with the infinite-layer crystal structure have been synthesized in thin film and powder form via topotactic oxygen reduction of the perovskite phase. The infinite-layer phase exhibits remarkable properties, such as superconducti
We report an x-ray emission spectroscopy (XES) study of the local fluctuating magnetic moment ($mu_{bare}$) in $mathrm{NaFe_{1-x}Co_{x}As}$ and $mathrm{NaFe_{1-x}Cu_{x}As}$. In NaFeAs, the reduced height of the As ions induces a local magnetic moment
A new layered iron arsenide NaFeAs isostructural with the superconducting lithium analogue, displays evidence for the coexistence of superconductivity and magnetic ordering.