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CaFe$_2$As$_2$ has been synthesized and found to form in the tetragonal, ThCr$_2$Si$_2$ structure with lattice parameters $a = 3.912(68) AA$ and $c = 11.667(45) AA$. Upon cooling through 170 K, CaFe$_2$As$_2$ undergoes a first order, structural phase transition to a low temperature, orthorhombic phase with a $2 - 3$ K range of hysteresis and coexistence. This transition is clearly evident in microscopic, thermodynamic and transport measurements. CaFe$_2$As$_2$ is the third member of the AFe$_2$As$_2$ (A = Ba, Sr, Ca) family to exhibit such a dramatic phase transition and is a promising candidate for studies of doping induced superconductivity.
Iron-based compounds (IBS) display a surprising variety of superconducting properties that seems to arise from the strong sensitivity of these systems to tiny details of the lattice structure. In this respect, systems that become superconducting unde
We report the synthesis and basic physical properties of single crystals of CaFe2As2, an isostructural compound to BaFe2As2 which has been recently doped to produce superconductivity. CaFe2As2 crystalizes in the ThCr2Si2 structure with lattice parame
The very nature of the ground state of the pyrochlore compound Yb$_2$Ti$_2$O$_7$ is much debated, as experimental results demonstrate evidence for both a disordered or a long-range ordered ground state. Indeed, the delicate balance of exchange intera
We investigate the crystal structure and lattice vibrations of Sr$_2$IrO$_4$ by a combined phonon Raman scattering and x-ray powder diffraction experiment under pressures up to $66$ GPa and room temperature. Density functional theory (DFT) and $ab$-i
Taking the pseudobinary C15 Laves phase compound Ce(Fe$_{0.96}$Al$_{0.04}$)$_2$ as a paradigm for studying a ferromagnetic to antiferromagnetic phase transition, we present interesting thermomagnetic history effects in magnetotransport as well as mag