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تسجيل مستخدم جديدNonlinear NMR dynamics in hyperpolarized liquid 3He
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تأليف
Emmanuel Baudin
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In a highly polarized liquid (laser-polarized 3He-4He mixtures in our experiment), dipolar magnetic interactions within the liquid introduce a significant nonlinear and nonlocal contribution to the Bloch equation that leads to instabilities during NMR evolution. We have launched a study of these instabilities using spin echo techniques. At high magnetizations, a simple 180 degree rf pulse fails to refocus magnetization, so we use a standard solid-state NMR pulse sequence: the magic sandwich. We report an experimental and numerical investigation of the effect of this sequence on unstable NMR evolution. Using a series of repeated magic sandwich sequences, the transverse magnetization lifetime can be increased by up to three orders of magnitude.
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Long-range magnetic interactions in highly magnetised liquids (laser-polarised 3He-4He dilute mixtures at 1 K in our experiment) introduce a significant non-linear and non-local contribution to the evolution of nuclear magnetisation that leads to ins
tabilities during free precession. We recently demonstrated that a multi-echo NMR sequence, based on the magic sandwich pulse scheme developed for solid-state NMR, can be used to stabilise the magnetisation against the effect of distant dipolar fields. Here, we report investigations of echo attenuation in an applied field gradient that show the potential of this NMR sequence for spin diffusion measurements at high magnetisation densities.
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