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We report the discovery of propylene (also called propene, CH_2CHCH_3) with the IRAM 30-m radio telescope toward the dark cloud TMC-1. Propylene is the most saturated hydrocarbon ever detected in space through radio astronomical techniques. In spite of its weak dipole moment, 6 doublets (A and E species) plus another line from the A species have been observed with main beam temperatures above 20 mK. The derived total column density of propylene is 4 10^13 cm^-2, which corresponds to an abundance relative to H_2 of 4 10^-9, i.e., comparable to that of other well known and abundant hydrocarbons in this cloud, such as c-C_3H_2. Although this isomer of C_3H_6 could play an important role in interstellar chemistry, it has been ignored by previous chemical models of dark clouds as there seems to be no obvious formation pathway in gas phase. The discovery of this species in a dark cloud indicates that a thorough analysis of the completeness of gas phase chemistry has to be done.
Life on Earth relies on chiral molecules, that is, species not superimposable on their mirror images. This manifests itself in the selection of a single molecular handedness, or homochirality, across the biosphere. We present the astronomical detecti
Networks of reactions on dust grain surfaces play a crucial role in the chemistry of interstellar clouds, leading to the formation of molecular hydrogen in diffuse clouds as well as various organic molecules in dense molecular clouds. Due to the sub-
We discuss the first astronomical detection of the CF+ (fluoromethylidynium) ion, obtained by observations of the J=1-0 (102.6 GHz), J=2-1 (205.2 GHz) and J=3-2 (307.7 GHz) rotational transitions toward the Orion Bar region. Our search for CF+, carri
Chemical models used to study the chemical composition of the gas and the ices in the interstellar medium are based on a network of chemical reactions and associated rate coefficients. These reactions and rate coefficients are partially compiled from
We report the detection of linear and cyclic isomers of C3H and C3H2 towards various starless cores and review the corresponding chemical pathways involving neutral (C3Hx with x=1,2) and ionic (C3Hx+ with x = 1,2,3) isomers. We highlight the role of