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[Abridged] Investigations of neutron(n)-capture element nucleosynthesis and chemical evolution have largely been based on stellar spectroscopy. However, the recent detection of these elements in several planetary nebulae (PNe) indicates that nebular spectroscopy is a promising new tool for such studies. In PNe, n-capture element abundance determinations reveal details of s-process nucleosynthesis and convective mixing in evolved low-mass stars, as well as the chemical evolution of elements that cannot be detected in stellar spectra. Only one or two ions of a given trans-iron element can typically be detected in individual nebulae. Elemental abundance determinations thus require corrections for the abundances of unobserved ions. Such corrections rely on the availability of atomic data for processes that control the ionization equilibrium of nebulae. Until recently, these data were unknown for virtually all n-capture element ions. For the first five ions of Se, Kr, and Xe -- the three most widely detected n-capture elements in PNe -- we are calculating photoionization cross sections and radiative and dielectronic recombination rate coefficients using the multi-configuration Breit-Pauli atomic structure code AUTOSTRUCTURE. Charge transfer rate coefficients are being determined with a multichannel Landau-Zener code. To calibrate these calculations, we have measured absolute photoionization cross sections of Se and Xe ions at the Advanced Light Source synchrotron radiation facility. These atomic data can be incorporated into photoionization codes, which we will use to derive ionization corrections (hence abundances) for Se, Kr, and Xe in ionized nebulae. These results are critical for honing nebular spectroscopy into a more effective tool for investigating the production and chemical evolution of trans-iron elements in the Universe.
We constrain the iron abundance in a sample of 33 low-ionization Galactic planetary nebulae (PNe) using [Fe III] lines and correcting for the contribution of higher ionization states with ionization correction factors (ICFs) that take into account un
Neutron(n)-capture elements (atomic number Z>30), which can be produced in planetary nebula (PN) progenitor stars via s-process nucleosynthesis, have been detected in nearly 100 PNe. This demonstrates that nebular spectroscopy is a potentially powerf
Atomic data are an important source of systematic uncertainty in our determinations of nebular chemical abundances. However, we do not have good estimates of these uncertainties since it is very difficult to assess the accuracy of the atomic data inv
We study the density structures of planetary nebulae implied by four diagnostics that sample different regions within the nebulae: [S II] $lambda6716/lambda6731$, [O II] $lambda3726/lambda3729$, [Cl III] $lambda5518/lambda5538$, and [Ar IV] $lambda47
We study the dust present in 56 Galactic planetary nebulae (PNe) through their iron depletion factors, their C/O abundance ratios (in 51 objects), and the dust features that appear in their infrared spectra (for 33 objects). Our sample objects have d