Absorption-line spectroscopy is a powerful tool used to estimate element abundances in the nearby as well as distant universe. The accuracy of the abundances thus derived is, naturally, limited by the accuracy of the atomic data assumed for the spect
ral lines. We have recently started a project to perform the new extensive atomic data calculations used for optical/UV spectral lines in the plasma modeling code Cloudy using state-of-the-art quantal calculations. Here we demonstrate our approach by focussing on S II, an ion used to estimate metallicities for Milky Way interstellar clouds as well as distant damped Lyman-alpha (DLA) and sub-DLA absorber galaxies detected in the spectra of quasars and gamma-ray bursts (GRBs). We report new extensive calculations of a large number of energy levels of S II, and the line strengths of the resulting radiative transitions. Our calculations are based on the configuration interaction approach within a numerical Hartree-Fock framework, and utilize both non-ralativistic and quasirelativistic one-electron radial orbitals. The results of these new atomic calculations are then incorporated into Cloudy and applied to a lab plasma, and a typical DLA, for illustrative purposes. The new results imply relatively modest changes (~0.04 dex) to the metallicities estimated from S II in past studies. These results will be readily applicable to other studies of S II in the Milky Way and other galaxies.
We report the discovery of a super-damped Lyman-alpha absorber at $z_{abs}=2.2068$ toward QSO Q1135-0010 in the Sloan Digital Sky Survey, and follow-up VLT UVES spectroscopy. Voigt profile fit to the DLA line indicates log $N_{rm H I} = 22.05 pm 0.1$
. This is the second QSO DLA discovered to date with such high $N_{rm H I}$. We derive element abundances [Si/H] = $-1.10 pm 0.10$, [Zn/H] = $-1.06 pm 0.10$, [Cr/H] = $-1.55 pm 0.10$, [Ni/H] = $-1.60 pm 0.10$, [Fe/H] = $-1.76 pm 0.10$, [Ti/H] = $-1.69 pm 0.11$, [P/H] = $-0.93 pm 0.23$, and [Cu/H] = $-0.75 pm 0.14$. Our data indicate detection of Ly-$alpha$ emission in the DLA trough, implying a star formation rate of $sim$10 $M_{odot}$ yr$^{-1}$ in the absence of dust attenuation. C II$^{*} , lambda 1336$ absorption is also detected, suggesting SFR surface density $-2 < {rm log} , dot{psi_{*}} < 0$ $M_{odot}$ yr$^{-1}$ kpc$^{-2}$. We estimate electron density in the range $3.5 times 10^{-4}$ to 24.7 cm$^{-3}$ from C II$^{*}$/C II, and $sim$0.5-0.9 cm$^{-3}$ from Si II$^{*}$/Si II. Overall, this is a robustly star-forming, moderately enriched absorber, but with relatively low dust depletion. Fitting of the SDSS spectrum yields low reddening for Milky Way, LMC, or SMC extinction curves. No CO absorption is detected, and C I absorption is weak. The low dust and molecular content, reminiscent of some SMC sight-lines, may result from the lower metallicity, and a stronger radiation field (due to higher SFR). Finally, we compare this absorber with other QSO and GRB DLAs.
We report a detection of the 9.7 micrometer silicate absorption feature in a damped Lyman-alpha (DLA) system at z_{abs} = 0.524 toward AO0235+164, using the Infrared Spectrograph (IRS) onboard the Spitzer Space Telescope. The feature shows a broad sh
allow profile over about 8-12 micrometers in the absorber rest frame and appears to be > 15 sigma significant in equivalent width. The feature is fit reasonably well by the silicate absorption profiles for laboratory amorphous olivine or diffuse Galactic interstellar clouds. To our knowledge, this is the first indication of 9.7 micrometer silicate absorption in a DLA. We discuss potential implications of this finding for the nature of the dust in quasar absorbers. Although the feature is relatively shallow (tau_{9.7} = 0.08-0.09), it is about 2 times deeper than expected from extrapolation of the tau_{9.7} vs. E(B-V) relation known for diffuse Galactic interstellar clouds. Further studies of the 9.7 micrometer silicate feature in quasar absorbers will open a new window on the dust in distant galaxies.
