Deep observations of O2 toward a low-mass protostar with Herschel-HIFI

According to traditional gas-phase chemical models, O2 should be abundant in molecular clouds, but until recently, attempts to detect interstellar O2 line emission with ground- and space-based observatories have failed. Following the multi-line detections of O2 with low abundances in the Orion and rho Oph A molecular clouds with Herschel, it is important to investigate other environments, and we here quantify the O2 abundance near a solar-mass protostar. Observations of O2, at 487 GHz toward a deeply embedded low-mass Class 0 protostar, NGC 1333-IRAS 4A, are presented, using the HIFI instrument on the Herschel Space Observatory. Complementary data of the chemically related NO and CO molecules are obtained as well. The high spectral resolution data are analysed using radiative transfer models to infer column densities and abundances, and are tested directly against full gas-grain chemical models. The deep HIFI spectrum fails to show O2 at the velocity of the dense protostellar envelope, implying one of the lowest abundance upper limits of O2/H2 at <6x10^-9 (3 sigma). However, a tentative (4.5 sigma) detection of O2 is seen at the velocity of the surrounding NGC 1333 molecular cloud, shifted by 1 km/s relative to the protostar. For the protostellar envelope, pure gas-phase models and gas-grain chemical models require a long pre-collapse phase (~0.7-1x10^6 years), during which atomic and molecular oxygen are frozen out onto dust grains and fully converted to H2O, to avoid overproduction of O2 in the dense envelope. The same model also reproduces the limits on the chemically related NO molecule. The tentative detection of O2 in the surrounding cloud is consistent with a low-density PDR model with small changes in reaction rates. The low O2 abundance in the collapsing envelope around a low-mass protostar suggests that the gas and ice entering protoplanetary disks is very poor in O2.

Energetic processes revealed by spectrally resolved high-J CO lines in low-mass star-forming regions with Herschel-HIFI

Herschel-HIFI observations of high-J lines (up to J_u=10) of 12CO, 13CO and C18O are presented toward three deeply embedded low-mass protostars in NGC1333. The observations show several energetic components including shocked and quiescent gas. Radiative transfer models are used to quantify the C18O envelope abundance which require a jump in the abundance at an evaporation temperature, T_ev ~25 K, providing new direct evidence of a CO ice evaporation zone around protostars. The abundance in the outermost part of the envelope, X_0, is within the canonical value of 2x10^-4; however the inner abundance, X_in, is found around a factor of 3-5 lower than X_0.

Herschel-HIFI observations of high-J CO lines in the NGC 1333 low-mass star-forming region

Herschel-HIFI observations of high-J lines (up to J_u=10) of 12CO, 13CO and C18O are presented toward three deeply embedded low-mass protostars, NGC 1333 IRAS 2A, IRAS 4A, and IRAS 4B, obtained as part of the Water In Star-forming regions with Herschel (WISH) key program. The spectrally-resolved HIFI data are complemented by ground-based observations of lower-J CO and isotopologue lines. The 12CO 10-9 profiles are dominated by broad (FWHM 25-30 km s^-1) emission. Radiative transfer models are used to constrain the temperature of this shocked gas to 100-200 K. Several CO and 13CO line profiles also reveal a medium-broad component (FWHM 5-10 km s^-1), seen prominently in H2O lines. Column densities for both components are presented, providing a reference for determining abundances of other molecules in the same gas. The narrow C18O 9-8 lines probe the warmer part of the quiescent envelope. Their intensities require a jump in the CO abundance at an evaporation temperature around 25 K, thus providing new direct evidence for a CO ice evaporation zone around low-mass protostars.