Instanton calculations in semiclassical quantum mechanics rely on integration along trajectories which solve classical equations of motion. However in systems with higher dimensionality or complexified phase space these are rarely attainable. A prime
example are spin-coherent states which are used e.g. to describe single molecule magnets (SMM). We use this example to develop instanton calculus which does not rely on explicit solutions of the classical equations of motion. Energy conservation restricts the complex phase space to a Riemann surface of complex dimension one, allowing to deform integration paths according to Cauchys integral theorem. As a result, the semiclassical actions can be evaluated without knowing actual classical paths. Furthermore we show that in many cases such actions may be solely derived from monodromy properties of the corresponding Riemann surface and residue values at its singular points. As an example, we consider quenching of tunneling processes in SMM by an applied magnetic field.
Statistical mechanics of 1D multivalent Coulomb gas may be mapped onto non-Hermitian quantum mechanics. We use this example to develop instanton calculus on Riemann surfaces. Borrowing from the formalism developed in the context of Seiberg-Witten dua
lity, we treat momentum and coordinate as complex variables. Constant energy manifolds are given by Riemann surfaces of genus $ggeq 1$. The actions along principal cycles on these surfaces obey ODE in the moduli space of the Riemann surface known as Picard-Fuchs equation. We derive and solve Picard-Fuchs equations for Coulomb gases of various charge content. Analysis of monodromies of these solutions around their singular points yields semiclassical spectra as well as instanton effects such as Bloch bandwidth. Both are shown to be in perfect agreement with numerical simulations.
