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Inelastic x-ray scattering and $ab$-$initio$ calculation are applied to investigate the lattice dynamics and electron-phonon coupling of the ternary silicide superconductor CaAlSi ($P/bar{6}m2$). A soft c-axis polarized mode is clearly observed along the $/Gamma$-$A$-$L$ symmetry directions. The soft mode is strongly anharmonically broadened at room temperature, but, at 10 K, its linewidth narrows and becomes in good agreement with calculations of linear electron-phonon coupling. This establishes a coherent description of the detailed phonon properties in this system and links them clearly and consistently with the superconductivity.
A complex structure of the superconducting order parameter in $Ln_2$C$_3$ ($Ln$ = La, Y) is demonstrated by muon spin relaxation ($mu$SR) measurements in their mixed state. The muon depolarization rate [$sigma_{rm v}(T)$] exhibits a characteristic te mperature dependence that can be perfectly described by a phenomenological double-gap model for nodeless superconductivity. While the magnitude of two gaps is similar between La$_2$C$_3$ and Y$_2$C$_3$, a significant difference in the interband coupling between those two cases is clearly observed in the behavior of $sigma_{rm v}(T)$.
The full-potential linear augmented plane-wave calculations have been applied to investigate the systematic change of electronic structures in CaAlSi due to different stacking sequences of AlSi layers. The present ab-initio calculations have revealed that the multistacking, buckling and 60 degrees rotation of AlSi layer affect the electronic band structure in this system. In particular, such a structural perturbation gives rise to the disconnected and cylindrical Fermi surface along the M-L lines of the hexagonal Brillouin zone. This means that multistacked CaAlSi with the buckling AlSi layers increases degree of two-dimensional electronic characters, and it gives us qualitative understanding for the quite different upper critical field anisotropy between specimens with and without superstructure as reported previously.
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