The nearby Sy 1 galaxy NGC 1097 represents an ideal laboratory to explore the molecular chemistry in the presence and surroundings of an active galactic nucleus. Exploring the distribution of different molecular species allows us to understand the ph
ysical processes affecting the ISM both in the AGN vicinity as well as in the outer star forming molecular ring. We carried out 3 mm ALMA observations of HCN, HCO+, CCH, CS, HNCO, SiO, HC3N, and SO as well as the 13C isotopologues. All species were imaged over the central 2 kpc (~30) of the galaxy at a resolution of ~2.2x1.5 (150 pc x 100 pc). HCO+ and CS appear to be slightly enhanced in the star forming ring. CCH, showing the largest variations across NGC 1097, is suggested to be a good tracer of both obscured and early stage star formation. HNCO, SiO and HC3N are significantly enhanced in the inner circumnuclear disk surrounding the AGN. Differences in the molecular abundances are observed between the star forming ring and the inner circumnuclear disk. We conclude that the HCN/HCO+ and HCN/CS differences observed between AGN dominated and starburst galaxies are not due to a HCN enhancement due to X-rays, but rather this enhancement is produced by shocked material at distances of 200 pc from the AGN. Additionally we claim the lower HCN/CS to be a combination of a small under-abundance of CS in AGNs together with excitation effects, where a high dense gas component (~10^6 cm^-3) may be more prominent in SB galaxies. However the most promising are the differences found among the dense gas tracers which, at our modest spatial resolution, seem to outline the physical structure of the molecular disk around the AGN. In this picture, HNCO probes the well shielded gas in the disk, surrounding the dense material moderately exposed to X-ray radiation traced by HC3N. Finally SiO might be the innermost molecule in the disk structure.
The interstellar region within the few central parsecs around the super-massive black hole, Sgr A* at the very Galactic center is composed by a number of overlapping molecular structures which are subject to one of the most hostile physical environme
nts in the Galaxy. We present high resolution (4x3~0.16x0.11 pc) interferometric observations of CN, 13CN, H2CO, SiO, c-C3H2 and HC3N emission at 1.3 mm towards the central ~4 pc of the Galactic center region. Strong differences are observed in the distribution of the different molecules. The UV resistant species CN, the only species tracing all previously identified circumnuclear disk (CND) structures, is mostly concentrated in optically thick clumps in the rotating filaments around Sgr A*. H2CO emission traces a shell-like structure that we interpret as the expansion of Sgr A East against the 50 km/s and 20 km/s giant molecular clouds (GMCs). We derive isotopic ratios 12C/13C~15-45 across most of the CND region. The densest molecular material, traced by SiO and HC3N, is located in the southern CND. The observed c-C3H2/HC3N ratio observed in the region is more than an order of magnitude lower than in Galactic PDRs. Toward the central region only CN was detected in absorption. Apart from the known narrow line-of-sight absorptions, a 90 km/s wide optically thick spectral feature is observed. We find evidences of an even wider (>100 km/s) absorption feature. Around 70-75% of the gas mass, concentrated in just the 27% densest molecular clumps, is associated with rotating structures and show evidences of association with each of the arcs of ionized gas in the mini-spiral structure. Chemical differentiation has been proven to be a powerful tool to disentangle the many overlapping molecular components in this crowded and heavily obscured region.
We present the first aperture synthesis unbiased spectral line survey toward an extragalactic object. The survey covered the 40 GHz frequency range between 202 and 242 GHz of the 1.3 mm atmospheric window. We find that 80% of the observed band shows
molecular emission, with 73 features identified from 15 molecular species and 6 isotopologues. The 13C isotopic substitutions of HC3N and transitions from H2(18)O, 29SiO, and CH2CO are detected for the first time outside the Galaxy. Within the broad observed band, we estimate that 28% of the total measured flux is due to the molecular line contribution, with CO only contributing 9% to the overall flux. We present maps of the CO emission at a resolution of 2.9x1.9 which, though not enough to resolve the two nuclei, recover all the single-dish flux. The 40 GHz spectral scan has been modelled assuming LTE conditions and abundances are derived for all identified species. The chemical composition of Arp 220 shows no clear evidence of an AGN impact on the molecular emission but seems indicative of a purely starburst-heated ISM. The overabundance of H2S and the low isotopic ratios observed suggest a chemically enriched environment by consecutive bursts of star formation, with an ongoing burst at an early evolutionary stage. The large abundance of water (~10^-5), derived from the isotopologue H2(18)O, as well as the vibrationally excited emission from HC3N and CH3CN are claimed to be evidence of massive star forming regions within Arp 220. Moreover, the observations put strong constraints on the compactness of the starburst event in Arp 220. We estimate that such emission would require ~2-8x10^6 hot cores, similar to those found in the Sgr B2 region in the Galactic center, concentrated within the central 700 pc of Arp 220.
