Ubiquitous argonium (ArH$^+$) in the diffuse interstellar medium -- a molecular tracer of almost purely atomic gas

We describe the assignment of a previously unidentified interstellar absorption line to ArH$^+$ and discuss its relevance in the context of hydride absorption in diffuse gas with a low H$_2$ fraction. The column densities along several lines of sight are determined and discussd in the framework of chemical models. The column densities of ArH$^+$ are compared to those of other species, tracing interstellar medium (ISM) components with different H$_2$ abundances. Chemical models are constructed, taking UV radiation and cosmic ray ionization into account. Due to the detection of two isotopologues, $^{36}$ArH$^+$ and $^{38}$ArH$^+$, we are confident about the carrier assignment to ArH$^+$. NeH$^+$ is not detected with a limit of [NeH$^+$]/[ArH$^+$] $le$ 0.1. The derived column densities agree well with the predictions of chemical models. ArH$^+$ is a unique tracer of gas with a fractional H$_2$ abundance of $10^{-4}- 10^{-3}$ and shows little correlation with H$_2$O$^+$, which traces gas with a fractional H$_2$ abundance of $approx $0.1. A careful analysis of variations in the ArH$^+$, OH$^+$, H$_2$O$^+$ and HF column densities promises to be a faithful tracer of the distribution of the H$_2$ fractional abundance, providing unique information on a poorly known phase in the cycle of interstellar matter, its transition from atomic diffuse gas to dense molecular gas traced by CO emission. Abundances of these species put strong observational constraints upon magnetohydrodynamical (MHD) simulations of the interstellar medium, and potentially could evolve into a tool to characterize the ISM. Paradoxically, the ArH$^+$ molecule is a better tracer of ew{almost} purely atomic hydrogen gas than H{sc i} itself, since H{sc i} can also be present in gas with a significant molecular content, but ArH$^+$ singles out gas that is $>99.9$% atomic.

Reversal of infall in SgrB2(M) revealed by Herschel/HIFI observations of HCN lines at THz frequencies

To investigate the accretion and feedback processes in massive star formation, we analyze the shapes of emission lines from hot molecular cores, whose asymmetries trace infall and expansion motions. The high-mass star forming region SgrB2(M) was observed with Herschel/HIFI (HEXOS key project) in various lines of HCN and its isotopologues, complemented by APEX data. The observations are compared to spherically symmetric, centrally heated models with density power-law gradient and different velocity fields (infall or infall+expansion), using the radiative transfer code RATRAN. The HCN line profiles are asymmetric, with the emission peak shifting from blue to red with increasing J and decreasing line opacity (HCN to H$^{13}$CN). This is most evident in the HCN 12--11 line at 1062 GHz. These line shapes are reproduced by a model whose velocity field changes from infall in the outer part to expansion in the inner part. The qualitative reproduction of the HCN lines suggests that infall dominates in the colder, outer regions, but expansion dominates in the warmer, inner regions. We are thus witnessing the onset of feedback in massive star formation, starting to reverse the infall and finally disrupting the whole molecular cloud. To obtain our result, the THz lines uniquely covered by HIFI were critically important.

Herschel observations of deuterated water towards Sgr B2(M)

Observations of HDO are an important complement for studies of water, because they give strong constraints on the formation processes -- grain surfaces versus energetic process in the gas phase, e.g. in shocks. The HIFI observations of multiple transitions of HDO in Sgr~B2(M) presented here allow the determination of the HDO abundance throughout the envelope, which has not been possible before with ground-based observations only. The abundance structure has been modeled with the spherical Monte Carlo radiative transfer code RATRAN, which also takes radiative pumping by continuum emission from dust into account. The modeling reveals that the abundance of HDO rises steeply with temperature from a low abundance ($2.5times 10^{-11}$) in the outer envelope at temperatures below 100~K through a medium abundance ($1.5times 10^{-9}$) in the inner envelope/outer core, at temperatures between 100 and 200~K, and finally a high abundance ($3.5times 10^{-9}$) at temperatures above 200~K in the hot core.

Herschel observations of ortho- and para-oxidaniumyl (H2O+) in spiral arm clouds toward Sgr B2(M)

H2O+ has been observed in its ortho- and para- states toward the massive star forming core Sgr B2(M), located close to the Galactic center. The observations show absorption in all spiral arm clouds between the Sun and Sgr B2. The average o/p ratio of H2O+ in most velocity intervals is 4.8, which corresponds to a nuclear spin temperature of 21 K. The relationship of this spin temperature to the formation temperature and current physical temperature of the gas hosting H2O+ is discussed, but no firm conclusion is reached. In the velocity interval 0 to 60 km/s, an ortho/para ratio of below unity is found, but if this is due to an artifact of contamination by other species or real is not clear.