In order to determine the composition of the dust in the circumstellar envelopes of oxygen-rich asymptotic giant branch (AGB) stars we have computed a grid of modust radiative-transfer models for a range of dust compositions, mass-loss rates, dust sh
ell inner radii and stellar parameters. We compare the resulting colours with the observed oxygen-rich AGB stars from the SAGE-Spec Large Magellanic Cloud (LMC) sample, finding good overall agreement for stars with a mid-infrared excess. We use these models to fit a sample of 37 O-rich AGB stars in the LMC with optically thin circumstellar envelopes, for which 5$-$35-$mu$m Spitzer infrared spectrograph (IRS) spectra and broadband photometry from the optical to the mid-infrared are available. From the modelling, we find mass-loss rates in the range $sim 8times10^{-8}$ to $5times10^{-6}$ M$_{odot} mathrm{yr}^{-1}$, and we show that a grain mixture consisting primarily of amorphous silicates, with contributions from amorphous alumina and metallic iron provides a good fit to the observed spectra. Furthermore, we show from dust models that the AKARI [11]$-$[15] versus [3.2]$-$[7] colour-colour diagram, is able to determine the fractional abundance of alumina in O-rich AGB stars.
We investigate the occurrence of crystalline silicates in oxygen-rich evolved stars across a range of metallicities and mass-loss rates. It has been suggested that the crystalline silicate feature strength increases with increasing mass-loss rate, im
plying a correlation between lattice structure and wind density. To test this, we analyse Spitzer IRS and Infrared Space Observatory SWS spectra of 217 oxygen-rich asymptotic giant branch stars and 98 red supergiants in the Milky Way, the Large and Small Magellanic Clouds and Galactic globular clusters. These encompass a range of spectral morphologies from the spectrally-rich which exhibit a wealth of crystalline and amorphous silicate features to naked (dust-free) stars. We combine spectroscopic and photometric observations with the GRAMS grid of radiative transfer models to derive (dust) mass-loss rates and temperature. We then measure the strength of the crystalline silicate bands at 23, 28 and 33 microns. We detect crystalline silicates in stars with dust mass-loss rates which span over 3 dex, down to rates of ~10^-9 solar masses/year. Detections of crystalline silicates are more prevalent in higher mass-loss rate objects, though the highest mass-loss rate objects do not show the 23-micron feature, possibly due to the low temperature of the forsterite grains or it may indicate that the 23-micron band is going into absorption due to high column density. Furthermore, we detect a change in the crystalline silicate mineralogy with metallicity, with enstatite seen increasingly at low metallicity.
