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The concept of entanglement, in which coherent quantum states become inextricably correlated, has evolved from one of the most startling and controversial outcomes of quantum mechanics to the enabling principle of emerging technologies such as quantu m computation and quantum sensors. The use of entangled particles in measurement permits the transcendence of the standard quantum limit in sensitivity, which scales as N^1/2 for N particles, to the Heisenberg limit, which scales as N. This approach has been applied to optical interferometry using entangled photons and spin pairs for the measurement of magnetic fields and improvements on atomic clocks. Here, we demonstrate experimentally an 9.4-fold increase in sensitivity to an external magnetic field of a 10-spin entangled state, compared with an isolated spin, using nuclear spins in a highly symmetric molecule. This approach scales in a favourable way compared to systems where qubit loss is prevalent, and paves the way for enhanced precision in magnetic field sensing
The transfer of information between different physical forms is a central theme in communication and computation, for example between processing entities and memory. Nowhere is this more crucial than in quantum computation, where great effort must be taken to protect the integrity of a fragile quantum bit. Nuclear spins are known to benefit from long coherence times compared to electron spins, but are slow to manipulate and suffer from weak thermal polarisation. A powerful model for quantum computation is thus one in which electron spins are used for processing and readout while nuclear spins are used for storage. Here we demonstrate the coherent transfer of a superposition state in an electron spin processing qubit to a nuclear spin memory qubit, using a combination of microwave and radiofrequency pulses applied to 31P donors in an isotopically pure 28Si crystal. The electron spin state can be stored in the nuclear spin on a timescale that is long compared with the electron decoherence time and then coherently transferred back to the electron spin, thus demonstrating the 31P nuclear spin as a solid-state quantum memory. The overall store/readout fidelity is about 90%, attributed to systematic imperfections in radiofrequency pulses which can be improved through the use of composite pulses. We apply dynamic decoupling to protect the nuclear spin quantum memory element from sources of decoherence. The coherence lifetime of the quantum memory element is found to exceed one second at 5.5K.
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