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We report a time-series analysis of satellite photometry of the non-radially pulsating Oe star zeta Oph, principally using data from SMEI obtained 2003--2008, but augmented with MOST and WIRE results. Amplitudes of the strongest photometric signals, at 5.18, 2.96, and 2.67/d, each vary independently over the 6-year monitoring period (from ca. 30 to <2 mmag at 5.18/d), on timescales of hundreds of days. Signals at 7.19/d and 5.18/d have persisted (or recurred) for around two decades. Supplementary spectroscopic observations show an H-alpha emission episode in 2006; this coincided with small increases in amplitudes of the three strongest photometric signals.
We present extensive optical spectroscopy of the early-type magnetic star HD 191612 (O6.5f?pe-O8fp). The Balmer and HeI lines show strongly variable emission which is highly reproducible on a well-determined 538-d period. Metal lines and HeII absorpt ions (including many selective emission lines but excluding He II 4686A emission) are essentially constant in line strength, but are variable in velocity, establishing a double-lined binary orbit with P(orb) = 1542d, e=0.45. We conduct a model-atmosphere analysis of the primary, and find that the system is consistent with a O8: giant with a B1: main-sequence secondary. Since the periodic 538-d changes are unrelated to orbital motion, rotational modulation of a magnetically constrained plasma is strongly favoured as the most likely underlying `clock. An upper limit on the equatorial rotation is consistent with this hypothesis, but is too weak to provide a strong constraint.
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