Molecular complexity builds up at each step of the Sun-like star formation process, starting from simple molecules and ending up in large polyatomic species. Complex organic molecules (COMs; such as methyl formate, HCOOCH$_3$, dymethyl ether, CH$_3$O
CH$_3$, formamide, NH$_2$CHO, or glycoaldehyde, HCOCH$_2$OH) are formed in all the components of the star formation recipe (e.g. pre-stellar cores, hot-corinos, circumstellar disks, shocks induced by fast jets), due to ice grain mantle sublimation or sputtering as well as gas-phase reactions. Understanding in great detail the involved processes is likely the only way to predict the ultimate molecular complexity reached in the ISM, as the detection of large molecules is increasingly more difficult with the increase of the number of atoms constituting them. Thanks to the recent spectacular progress of astronomical observations, due to the Herschel (sub-mm and IR), IRAM and SMA (mm and sub-mm), and NRAO (cm) telescopes, an enormous activity is being developed in the field of Astrochemistry, extending from astronomical observatories to chemical laboratories. We are involved in several observational projects providing unbiased spectral surveys (in the 80-300 and 500-2000 GHz ranges) with unprecedented sensitivity of templates of dense cores and protostars. Forests of COM lines have been detected. In this chapter we will focus on the chemistry of both cold prestellar cores and hot shocked regions, (i) reviewing results and open questions provided by mm-FIR observations, and (ii) showing the need of carrying on the observations of COMs at lower frequencies, where SKA will operate. We will also emphasize the importance of analysing the spectra by the light of the experimental studies performed by our team, who is investigating the chemical effects induced by ionising radiation bombarding astrophysically relevant ices.
Context: The earliest evolutionary stages of low-mass protostars are characterised by hot and fast jets which remove angular momentum from the circumstellar disk, thus allowing mass accretion onto the central object. However, the launch mechanism is
still being debated. Aims: We would like to exploit high-angular (~ 0.8) resolution and high-sensitivity images to investigate the origin of protostellar jets using typical molecular tracers of shocked regions, such as SiO and SO. Methods: We mapped the inner 22 of the NGC1333-IRAS2A protostar in SiO(5-4), SO(65-54), and the continuum emission at 1.4 mm using the IRAM Plateau de Bure interferometer in the framework of the CALYPSO IRAM large program. Results: For the first time, we disentangle the NGC1333-IRAS2A Class 0 object into a proto-binary system revealing two protostars (MM1, MM2) separated by ~ 560 AU, each of them driving their own jet, while past work considered a single protostar with a quadrupolar outflow. We reveal (i) a clumpy, fast (up to |V-VLSR| > 50 km/s), and blueshifted jet emerging from the brightest MM1 source, and (ii) a slower redshifted jet, driven by MM2. Silicon monoxide emission is a powerful tracer of high-excitation (Tkin > 100 K; n(H2) > 10^5 cm-3) jets close to the launching region. At the highest velocities, SO appears to mimic SiO tracing the jets, whereas at velocities close to the systemic one, SO is dominated by extended emission, tracing the cavity opened by the jet. Conclusions: Both jets are intrinsically monopolar, and intermittent in time. The dynamical time of the SiO clumps is < 30-90 yr, indicating that one-sided ejections from protostars can take place on these timescales.
We present the first detection of N2H+ towards a low-mass protostellar outflow, namely the L1157-B1 shock, at about 0.1 pc from the protostellar cocoon. The detection was obtained with the IRAM 30-m antenna. We observed emission at 93 GHz due to the
J = 1-0 hyperfine lines. The analysis of the emission coupled with the HIFI CHESS multiline CO observations leads to the conclusion that the observed N2H+(1-0) line originates from the dense (> 10^5 cm-3) gas associated with the large (20-25 arcsec) cavities opened by the protostellar wind. We find a N2H+ column density of few 10^12 cm-2 corresponding to an abundance of (2-8) 10^-9. The N2H+ abundance can be matched by a model of quiescent gas evolved for more than 10^4 yr, i.e. for more than the shock kinematical age (about 2000 yr). Modelling of C-shocks confirms that the abundance of N2H+ is not increased by the passage of the shock. In summary, N2H+ is a fossil record of the pre-shock gas, formed when the density of the gas was around 10^4 cm-3, and then further compressed and accelerated by the shock.
Context: L1448-mm is the prototype of a low-mass Class 0 protostar driving a high-velocity jet. Given its bright H2O spectra observed with ISO, L1448-mm is an ideal laboratory to observe heavy water (HDO) emission. Aims: Our aim is to image the HDO e
mission in the protostar surroundings, the possible occurrence of HDO emission also investigating off L1448-mm, towards the molecular outflow. Methods: We carried out observations of L1448-mm in the HDO(1_10-1_11) line at 80.6 GHz, an excellent tracer of HDO column density, with the IRAM Plateau de Bure Interferometer. Results: We image for the first time HDO emission around L1448-mm. The HDO structure reveals a main clump at velocities close to the ambient one towards the the continuum peak that is caused by the dust heated by the protostar. In addition, the HDO map shows tentative weaker emission at about 2000 AU from the protostar towards the south, which is possibly associated with the walls of the outflow cavity opened by the protostellar wind. Conclusions: Using an LVG code, modelling the density and temperature profile of the hot-corino, and adopting a gas temperature of 100 K and a density of 1.5 10^8 cm^-3, we derive a beam diluted HDO column density of about 7 10^13 cm^-2, corresponding to a HDO abundance of about 4 10^-7. In addition, the present map supports the scenario where HDO can be efficiently produced in shocked regions and not uniquely in hot corinos heated by the newly born star.
