We present a detailed analysis of the production efficiency of weakly bound heteronuclear KRb-Feshbach molecules using radio frequency association in a harmonic trap. The efficiency was measured in a wide range of temperatures, binding energies and r
adio frequencies. A comprehensive analytical model is presented, explaining the observed asymmetric spectra and achieving good quantitative agreement with the measured production rates. This model provides a deep understanding of the molecule association process and paves the way for future experiments which rely on Feshbach molecules e.g. for the production of deeply bound molecules.
We have observed 28 heteronuclear Feshbach resonances in 10 spin combinations of the hyperfine ground states of a 40K 87Rb mixture. The measurements were performed by observing the loss rates from an atomic mixture at magnetic fields between 0 and 70
0 G. This data was used to significantly refine an interatomic potential derived from molecular spectroscopy, yielding a highly consistent model of the KRb interaction. Thus, the measured resonances can be assigned to the corresponding molecular states. In addition, this potential allows for an accurate calculation of the energy differences between highly excited levels and the rovibrational ground level. This information is of particular relevance for the formation of deeply bound heteronuclear molecules. Finally, the model is used to predict Feshbach resonances in mixtures of 87Rb combined with 39K or 41K.
