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In this work we report the performances and the chemical and physical properties of a (2 x 1.2) ton organic liquid scintillator target doped with Gd up to ~0.1%, and the results of a 2 year long stability survey. In particular we have monitored the a mount of both Gd and primary fluor actually in solution, the optical and fluorescent properties of the Gd-doped liquid scintillator (GdLS) and its performances as a neutron detector, namely neutron capture efficiency and average capture time. The experimental survey is ongoing, the target being continuously monitored. After two years from the doping time the performances of the Gd-doped liquid scintillator do not show any hint of degradation and instability; this conclusion comes both from the laboratory measurements and from the in-tank measurements. This is the largest stable Gd-doped organic liquid scintillator target ever produced and continuously operated for a long period.
A novel formulation to dope organic liquid scintillators (OLS) with indium at concentrations up to 10% is presented: it is based on specific indium carboxylate compounds adequately synthesized. The produced In-OLS has been characterized: it has light yield 8500 ph/MeV at indium concentration 5.5% and light attenuation length of 2,5 m at wavelength of 430 nm. The scintillator properties were stable during all time of investigation (~ 1 years). The produced In-OLS is compared to other In-OLS formulations and shows superior performances. The developed methodic to metal dope OLS can be easily extended to other metals as Gd, Nd, Cd.
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