To investigate the superconducting (SC) state near a charge instability, we performed ^{13}C NMR experiments on the molecular superconductor beta-(BEDT-TTF)_{4}[(H_{3}O)Ga(C_{2}O_{4})_{3}]C_{6}H_{5}NO_{2}, which exhibits a charge anomaly at 100 K. Th
e Knight shift which we measured in the SC state down to 1.5 K demonstrates that Cooper pairs are in spin-singlet state. Measurements of the nuclear spin-lattice relaxation time reveal strong electron-electron correlations in the normal state. The resistivity increase observed below 10 K indicates that the enhanced fluctuation has an electric origin. We discuss the possibility of charge-fluctuation-induced superconductivity.
We have performed ^{59}Co-nuclear quadrupole resonance (NQR) and nuclear magnetic resonance (NMR) studies on YCoGe, which is a reference compound of ferromagnetic superconductor UCoGe, in order to investigate the magnetic properties at the Co site. M
agnetic and superconducting transitions were not observed down to 0.3 K, but a conventional metallic behavior was found in YCoGe, although its crystal structure is similar to that of UCoGe. From the comparison between experimental results of two compounds, the ferromagnetism and superconductivity observed in UCoGe originate from the U-5f electrons.
We report an NMR and magnetometry study on the expanded intercalated fulleride Cs_3C_60 in both its A15 and face centered cubic structures. NMR allowed us to evidence that both exhibit a first-order Mott transition to a superconducting (SC) state, oc
curing at distinct critical pressures p_c and temperatures T_c. Though the ground state magnetism of the Mott phases differs, their high $T$ paramagnetic and SC properties are found similar, and the phase diagrams versus unit volume per C_60 are superimposed. Thus, as expected for a strongly correlated system, the inter-ball distance is the relvevant parameter driving the electronic behavior and quantum transitions of these systems.
