We present the single-crystalline x-ray diffraction study on the Ba4Ru3O10 consisting of the corner-shared Ru3O12 trimers. The crystal structure is re-determined from 78 to 300 K across an antiferromagnetic transition at 105 K. The orthorhombic symme
try (Cmca, space group No. 64) is preserved at all temperatures measured. This structure presents exceptionally long Ru-O distances characterized by a significant distribution within the Ru3O12 trimer. A bond valence sum calculation suggests that the charge disproportionation within the Ru3O12 trimer emerges even at room temperature, which we ascribe to molecular orbital formation in the Ru3O12 trimer, as supported by recent theoretical calculations. Based on the analyzed crystal structure, the electronic states and the nature of the phase transition at 105 K are discussed.
