We report Hall measurement of the normal state in K- and Co-doped BaFe$_2$As$_2$, as well NaFe$_{1-x}$Co$_x$As. We found that a power-law temperature dependence of Hall angle, cot$theta_{rm H}$$propto$ $T^beta$, prevails in normal state with temperat
ure range well above the structural, spin-density-wave and superconducting transitions for the all samples with various doping levels. The power $beta$ is nearly 4 for the parent compounds and the heavily underdoped samples, while around 3 for the superconducting samples. The $beta$ suddenly changes from 4 to 3 at a doping level that is close to the emergence of superconductivity. It suggests that the $beta$ of $sim 3$ is clearly tied to the superconductivity. Our data suggest that, similar to cuprates, there exists a connection between the physics in the normal state and superconductivity of iron-pnictides. These findings shed light on the mechanism of high-temperature superconductivity.
We report the structural, magnetic and electronic transport properties of SrFe$_{2-x}$Cu$_x$As$_2$ single crystals grown by self-flux technique. SrCu$_2$As$_2$ and SrFe$_2$As$_2$ both crystallize in ThCr$_2$Si$_2$-type (122-type) structure at room te
mperature, but exhibit distinct magnetic and electronic transport properties. The x-ray photoelectron spectroscopy(XPS) Cu-2p core line position, resistivity, susceptibility and positive Hall coefficient indicate that SrCu$_2$As$_2$ is an sp-band metal with Cu in the 3d$^{10}$ electronic configuration corresponding to the valence state Cu$^{1+}$. The almost unchanged Cu-2p core line position in SrFe$_{2-x}$Cu$_x$As$_2$ compared with SrCu$_2$As$_2$ indicates that partial Cu substitutions for Fe in SrFe$_2$As$_2$ may result in hole doping rather than the expected electron doping. No superconductivity is induced by Cu substitution on Fe sites, even though the structural/spin density wave(SDW) transition is gradually suppressed with increasing Cu doping.
We measured the resistivity and magnetic susceptibility to map out the phase diagram of single crystalline NaFe$_{1-x}$Co$_x$As. Replacement of Fe by Co suppresses both the structural and magnetic transition, while enhances the superconducting transi
tion temperature ($T_{rm c}$) and superconducting component fraction. Magnetic susceptibility exhibits temperature-linear dependence in the high temperatures up to 500 K for all the superconducting samples, but such behavior suddenly breaks down for the non-superconducting overdoped crystal, suggesting that the superconductivity is closely related to the T-linear dependence of susceptibility. Analysis on the superconducting-state specific heat for the optimally doped crystal provides strong evidence for a two-band s-wave order parameter with gap amplitudes of $Delta_1(0)/k_{rm B}T_{rm c}$= 1.78 and $Delta_2(0)/k_{rm B}T_{rm c}$=3.11, being consistent with the nodeless gap symmetry revealed by angle-resolved photoemission spectroscopy experiment.
We discover superconductivity in alkali-earth metals doped phenanthrene. The superconducting critical temperatures emph{T}$_c$ are 5.6 K and 5.4 K for Sr$_{1.5}$phenanthrene and Ba$_{1.5}$phenanthrene, respectively. The shielding fraction of Ba$_{1.5
}$phenanthrene exceeds 65%. The Raman spectra show 8 cm$^{-1}$/electron and 7 cm$^{-1}$/electron downshifts for the mode at 1441 cm$^{-1}$ due to the charge transfer to organic molecules from the dopants of Ba and Sr. Similar behavior has been observed in A$_3$phenanthrene and A$_3$C$_{60}$(A = K and Rb). The positive pressure effect in Sr$_{1.5}$phenanthrene and Ba$_{1.5}$phenanthrene together with the lower $T_c$ with larger lattice indicates unconventional superconductivity in this organic system.
