Quantum key distribution (QKD) gradually has become a crucial element of practical secure communication. In different scenarios, the security analysis of genuine QKD systems is complicated. A universal secret key rate calculation method, used for rea
listic factors such as multiple degrees of freedom encoding, asymmetric protocol structures, equipment flaws, environmental noise, and so on, is still lacking. Based on the correlations of statistical data, we propose a security analysis method without restriction on encoding schemes. This method makes a trade-off between applicability and accuracy, which can effectively analyze various existing QKD systems. We illustrate its ability by analyzing source flaws and a high-dimensional asymmetric protocol. Results imply that our method can give tighter bounds than the Gottesman-Lo-Lutkenhaus-Preskill (GLLP) analysis and is beneficial to analyze protocols with complex encoding structures. Our work has the potential to become a reference standard for the security analysis of practical QKD.
The appropriateness of including Hg among the transition metals has been debated for a long time. Although the synthesis of HgF$_{4}$ molecules in gas phase was reported before, the molecules show strong instabilities and dissociate. Therefore, the t
ransition metal propensity of Hg remains an open question. Here, we propose that high pressure provides a controllable method for preparing unusual oxidation states of matter. Using an advanced structure search method based on first-principles electronic structure calculations, we predict that under high pressures, Hg can transfer the electrons in its outmost $d$ shell to F atoms, thereby acting as a transition metal. Oxidation of Hg to the +4 state yielded thermodynamically stable molecular crystals consisting of HgF$_{4}$ planar molecules, a typical geometry for $d^{8}$ metal centers.
