Observations of flowing granular matter have suggested that same-material tribocharging de- pends on particle size, rendering large grains positive and small ones negative. Models assuming the transfer of trapped electrons can explain this, but so fa
r have not been validated. Tracking individual grains in an electric field, we show quantitatively that charge is transferred based on size between materially identical grains. However, the surface density of trapped electrons, measured independently by thermoluminescence techniques, is orders of magnitude too small to account for the scale of charge transferred. This suggests that another negatively charged species, such as ions, is responsible.
