We present 0.8-mm band molecular images and spectra obtained with the Atacama Large Millimeter/submillimeter Array (ALMA) toward one of the nearest galaxies with an active galactic nucleus (AGN), NGC 1068. Distributions of CO isotopic species ($^{13}
$CO and C$^{18}$O) $it{J}$ = 3--2, CN $it{N}$ = 3--2 and CS $it{J}$ = 7--6 are observed toward the circumnuclear disk (CND) and a part of the starburst ring with an angular resolution of $sim$1.$^{primeprime}$3 $times$ 1.$^{primeprime}$2. The physical properties of these molecules and shock-related molecules such as HNCO, CH$_{3}$CN, SO, and CH$_{3}$OH detected in the 3-mm band were estimated using rotation diagrams under the assumption of local thermodynamic equilibrium. The rotational temperatures of the CO isotopic species and the shock-related molecules in the CND are, respectively, 14--22 K and upper limits of 20--40 K. Although the column densities of the CO isotopic species in the CND are only from one-fifth to one-third of that in the starburst ring, those of the shock-related molecules are enhanced by a factor of 3--10 in the CND. We also discuss the chemistry of each species, and compare the fractional abundances in the CND and starburst ring with those of Galactic sources such as cold cores, hot cores, and shocked molecular clouds in order to study the overall characteristics. We find that the abundances of shock-related molecules are more similar to abundances in hot cores and/or shocked clouds than to cold cores. The CND hosts relatively complex molecules, which are often associated with shocked molecular clouds or hot cores. Because a high X-ray flux can dissociate these molecules, they must also reside in regions shielded from X-rays.
Sensitive observations with ALMA allow astronomers to observe the detailed distributions of molecules with relatively weak intensity in nearby galaxies. In particular, we report distributions of several molecular transitions including shock and dust
related species ($^{13}$CO $J$ = 1--0, C$^{18}$O $J$ = 1--0, $^{13}$CN $N$ = 1--0, CS $J$ = 2--1, SO $J_N$ = 3$_2$--2$_1$, HNCO $J_{Ka,Kc}$ = 5$_{0,5}$--4$_{0,4}$, HC$_3$N $J$ = 11--10, 12--11, CH$_3$OH $J_K$ = 2$_K$--1$_K$, and CH$_3$CN $J_K$ = 6$_K$--5$_K$) in the nearby Seyfert 2 galaxy NGC 1068 observed with the ALMA early science program. The central $sim$1 arcmin ($sim$4.3 kpc) of this galaxy was observed in the 100 GHz region covering $sim$96--100 GHz and $sim$108--111 GHz with an angular resolution of $sim4times2$ (290 pc$times$140 pc) to study the effects of an active galactic nucleus and its surrounding starburst ring on molecular abundances. Here, we present images and report a classification of molecular distributions into three main categories: (1) Molecules concentrated in the circumnuclear disk (CND) (SO $J_N$ = 3$_2$--2$_1$, HC$_3$N $J$ = 11--10, 12--11, and CH$_3$CN $J_K$ = 6$_K$--5$_K$), (2) Molecules distributed both in the CND and the starburst ring (CS $J$ = 2--1 and CH$_3$OH $J_K$ = 2$_K$--1$_K$), (3) Molecules distributed mainly in the starburst ring ($^{13}$CO $J$ = 1--0 and C$^{18}$O $J$ = 1--0). Since most of the molecules such as HC$_3$N observed in the CND are easily dissociated by UV photons and X-rays, our results indicate that these molecules must be effectively shielded. In the starburst ring, the relative intensity of methanol at each clumpy region is not consistent with those of $^{13}$CO, C$^{18}$O, and CS. This difference is probably caused by the unique formation and destruction mechanisms of CH$_3$OH.
We report a sensitive search for the rotational transitions of the carbon chain alcohol HC4OH in the frequency range of 21.2-46.7 GHz in the star-forming region L1527 and the dark cloud TMC-1. The motivation was laboratory detection of HC4OH by micro
wave spectroscopy. Despite achieving rms noise levels of several millikelvin in the antenna temperature using the 45 m telescope at Nobeyama Radio Observatory, the detection was not successful, leading to 3 sigma upper limits corresponding to the column densities of 2.0 times 1012 and 5.6 times 1012 cm-2 in L1527 and TMC-1, respectively. These upper limits indicate that [HC4OH]/[HC5N] ratios are less than 0.3 and 0.1 in L1527 and TMC-1, respectively, where HC5N is an HC4-chain cyanide and HC4OH is a hydroxide. These ratios suggest that the cyano carbon chain molecule dominates the hydroxyl carbon chain molecule in L1527 and TMC-1. This is contrary to the case of saturated compounds in hot cores, e.g., CH3OH and CH3CN, and can be a chemical feature of carbon chain molecules in L1527 and TMC-1. In addition, the column densities of the unsubstituted carbon chain molecule C4H and the sulfur-bearing molecules SO and HCS+ were determined from detected lines in L1527.
We used the Nobeyama 45-m telescope to conduct a spectral line survey in the 3-mm band (85.1-98.4 GHz) toward one of the nearest galaxies with active galactic nucleus NGC 1068 and the prototypical starburst galaxy NGC 253. The beam size of this teles
cope is ~18, which was sufficient to spatially separate the nuclear molecular emission from the emission of the circumnuclear starburst region in NGC 1068. We detected rotational transitions of C2H, cyclic-C3H2, and H13CN in NGC 1068. These are detections of carbon-chain and carbon-ring molecules in NGC 1068. In addition, the C2H N = 1-0 lines were detected in NGC 253. The column densities of C2H were determined to be 3.4 x 10^15 cm^-2 in NGC 1068 and 1.8 x 10^15 cm^-2 in NGC 253. The column densities of cyclic-C3H2 were determined to be 1.7 x 10^13 cm^-2 in NGC 1068 and 4.4 x 10^13 cm^-2 in NGC 253. We calculated the abundances of these molecules relative to CS for both NGC 1068 and NGC 253, and found that there were no significant differences in the abundances between the two galaxies. This result suggests that the basic carbon-containing molecules are either insusceptible to AGN, or are tracing cold (T_rot ~10 K) molecular gas rather than X-ray irradiated hot gas.
