Using an analogy to the classical Stefan problem, we construct evolution equations for the fluid pore pressure on both sides of a propagating stress-induced damage front. Closed form expressions are derived for the position of the damage front as a f
unction of time for the cases of thermally-induced damage as well as damage induced by over-pressure. We derive expressions for the flow rate during constant pressure fluid injection from the surface corresponding to a spherically shaped subsurface damage front. Finally, our model results suggest an interpretation of field data obtained during constant pressure fluid injection over the course of 16 days at an injection site near Desert Peak, NV.
Polyimides, due to their superior mechanical behavior at high temperatures, are used in a variety of applications that include aerospace, automobile and electronic packaging industries, as matrices for composites, as adhesives etc. In this paper, we
extend our previous model in [S. Karra, K. R. Rajagopal, Modeling the non-linear viscoelastic response of high temperature polyimides, Mechanics of Materials, In press, doi:10.1016/j.mechmat.2010.09.006], to include oxidative degradation of these high temperature polyimides. Appropriate forms for the Helmholtz potential and the rate of dissipation are chosen to describe the degradation. The results for a specific boundary value problem, using our model compares well with the experimental creep data for PMR-15 resin that is aged in air.
This paper is concerned with the diffusion of a fluid through a viscoelastic solid undergoing large deformations. Using ideas from the classical theory of mixtures and a thermodynamic framework based on the notion of maximization of the rate of entro
py production, the constitutive relations for a mixture of a viscoelastic solid and a fluid (specifically Newtonian fluid) are derived. By prescribing forms for the specific Helmholtz potential and the rate of dissipation, we derive the relations for the partial stress in the solid, the partial stress in the fluid, the interaction force between the solid and the fluid, and the evolution equation of the natural configuration of the solid. We also use the assumption that the volume of the mixture is equal to the sum of the volumes of the two constituents in their natural state as a constraint. Results from the developed model are shown to be in good agreement with the experimental data for the diffusion of various solvents through high temperature polyimides that are used in the aircraft industry. The swelling of a viscoelastic solid under the application of an external force is also studied.
A constitutive model is developed to predict the viscoelastic response of polyimide resins that are used in high temperature applications. This model is based on a thermodynamic framework that uses the notion that the `natural configuration of a body
evolves as the body undergoes a process and the evolution is determined by maximizing the rate of entropy production in general and the rate of dissipation within purely mechanical considerations. We constitutively prescribe forms for the specific Helmholtz potential and the rate of dissipation (which is the product of density, temperature and the rate of entropy production), and the model is derived by maximizing the rate of dissipation with the constraint of incompressibility, and the reduced energy dissipation equation is also regarded as a constraint in that it is required to be met in every process that the body undergoes. The efficacy of the model is ascertained by comparing the predictions of the model with the experimental data for PMR-15 and HFPE-II-52 polyimide resins.
We study the flow of a shear-thinning, chemically-reacting fluid that could be used to model the flow of the synovial fluid. The actual geometry where the flow of the synovial fluid takes place is very complicated, and therefore the governing equatio
ns are not amenable to simple mathematical analysis. In order to understand the response of the model, we choose to study the flow in a simple geometry. While the flow domain is not a geometry relevant to the flow of the synovial fluid in the human body it yet provides a flow which can be used to assess the efficacy of different models that have been proposed to describe synovial fluids. We study the flow in the annular region between two cylinders, one of which is undergoing unsteady oscillations about their common axis, in order to understand the quintessential behavioral characteristics of the synovial fluid. We use the three models suggested by Hron et al. [ J. Hron, J. M{a}lek, P. Pustv{e}jovsk{a}, K. R. Rajagopal, On concentration dependent shear-thinning behavior in modeling of synovial fluid flow, Adv. in Tribol. (In Press).] to study the problem, by appealing to a semi-inverse method. The assumed structure for the velocity field automatically satisfies the constraint of incompressibility, and the balance of linear momentum is solved together with a convection-diffusion equation. The results are compared to those associated with the Newtonian model. We also study the case in which an external pressure gradient is applied along the axis of the cylindrical annulus.
We study a variant of the well known Maxwell model for viscoelastic fluids, namely we consider the Maxwell fluid with viscosity and relaxation time depending on the pressure. Such a model is relevant for example in modelling behaviour of some polymer
s and geomaterials. Although it is experimentally known that the material moduli of some viscoelastic fluids can depend on the pressure, most of the studies concerning the motion of viscoelastic fluids do not take such effects into account despite their possible practical significance in technological applications. Using a generalized Maxwell model with pressure dependent material moduli we solve a simple boundary value problem and we demonstrate interesting non-classical features exhibited by the model.
In this paper, we apply the thermodynamic framework recently put into place by Rajagopal and co-workers, to develop rate-type models for viscoelastic fluids which do not possess instantaneous elasticity. To illustrate the capabilities of such models
we make a specific choice for the specific Helmholtz potential and the rate of dissipation and consider the creep and stress relaxation response associated with the model. Given specific forms for the Helmholtz potential and the rate of dissipation, the rate of dissipation is maximized with the constraint that the difference between the stress power and the rate of change of Helmholtz potential is equal to the rate of dissipation and any other constraint that may be applicable such as incompressibility. We show that the model that is developed exhibits fluid-like characteristics and is incapable of instantaneous elastic response. It also includes Maxwell-like and Kelvin-Voigt-like viscoelastic materials (when certain material moduli take special values).
Most three dimensional constitutive relations that have been developed to describe the behavior of bodies are correlated against one dimensional and two dimensional experiments. What is usually lost sight of is the fact that infinity of such three di
mensional models may be able to explain these experiments that are lower dimensional. Recently, the notion of maximization of the rate of entropy production has been used to obtain constitutive relations based on the choice of the stored energy and rate of entropy production, etc. In this paper we show different choices for the manner in which the body stores energy and dissipates energy and satisfies the requirement of maximization of the rate of entropy production that leads to many three dimensional models. All of these models, in one dimension, reduce to the model proposed by Burgers to describe the viscoelastic behavior of bodies.
The mechanical response and load bearing capacity of high performance polymer composites changes due to diffusion of a fluid, temperature, oxidation or the extent of the deformation. Hence, there is a need to study the response of bodies under such d
egradation mechanisms. In this paper, we study the effect of degradation and healing due to the diffusion of a fluid on the response of a solid which prior to the diffusion can be described by the generalized neo-Hookean model. We show that a generalized neo-Hookean solid - which behaves like an elastic body (i.e., it does not produce entropy) within a purely mechanical context - creeps and stress relaxes when infused with a fluid and behaves like a body whose material properties are time dependent. We specifically investigate the torsion of a generalized neo-Hookean circular cylindrical annulus infused with a fluid. The equations of equilibrium for a generalized neo-Hookean solid are solved together with the convection-diffusion equation for the fluid concentration. Different boundary conditions for the fluid concentration are also considered. We also solve the problem for the case when the diffusivity of the fluid depends on the deformation of the generalized neo-Hookean solid.
