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The transiting exoplanet WASP-18b was discovered in 2008 by the Wide Angle Search for Planets (WASP) project. The Spitzer Exoplanet Target of Opportunity Program observed secondary eclipses of WASP-18b using Spitzers Infrared Array Camera (IRAC) in t he 3.6 micron and 5.8 micron bands on 2008 December 20, and in the 4.5 micron and 8.0 micron bands on 2008 December 24. We report eclipse depths of 0.30 +/- 0.02%, 0.39 +/- 0.02%, 0.37 +/- 0.03%, 0.41 +/- 0.02%, and brightness temperatures of 3100 +/- 90, 3310 +/- 130, 3080 +/- 140 and 3120 +/- 110 K in order of increasing wavelength. WASP-18b is one of the hottest planets yet discovered - as hot as an M-class star. The planets pressure-temperature profile most likely features a thermal inversion. The observations also require WASP-18b to have near-zero albedo and almost no redistribution of energy from the day-side to the night side of the planet.
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