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We used the IRAM 30m telescope to observe the frequency range [86-116]GHz towards the central regions of the starburst galaxies M83, M82, and NGC253, the AGNs M51, NGC1068, and NGC7469, and the ULIRGs Arp220 and Mrk231. Assuming LTE conditions, we ca lculated the column densities of 27 molecules and 10 isotopologues. Among others, we report the first tentative detections of CH3CHO, HNCO, and NS in M82 and, for the first time in the extragalactic medium, HC5N in NGC253. Halpha recombination lines were only found in M82 and NGC253. Vibrationally excited lines of HC3N were only detected in Arp220. CH3CCH emission is only seen in the starburst-dominated galaxies. By comparison of the fractional abundances among the galaxies, we looked for the molecules that are best suited to characterise the chemistry of starbursts, AGNs and ULIRGs, as well as the differences among galaxies within the same group.
We aimed to study the molecular composition of the interstellar medium (ISM) surrounding an Active Galactic Nucleus (AGN), by making an inventory of molecular species and their abundances, as well as to establish a chemical differentiation between st arburst galaxies and AGN. We used the IRAM-30 m telescope to observe the central 1.5-2 kpc region of NGC1068, covering the frequencies between 86.2 GHz and 115.6 GHz. Using Boltzmann diagrams, we calculated the column densities of the detected molecules. We used a chemical model to reproduce the abundances found in the AGN, to determine the origin of each detected species, and to test the influence of UV fields, cosmic rays, and shocks on the ISM. We identified 24 different molecular species and isotopologues, among which HC3N, SO, N2H+, CH3CN, NS, 13CN, and HN13C are detected for the first time in NGC1068. We obtained the upper limits to the isotopic ratios 12C/13C=49, 16O/18O=177 and 32S/34S=5. Our chemical models suggest that the chemistry in the nucleus of NGC1068 is strongly influenced by cosmic rays, although high values of both cosmic rays and far ultraviolet (FUV) radiation fields also explain well the observations. The gas in the nucleus of NGC1068 has a different chemical composition as compared to starburst galaxies. The distinct physical processes dominating galaxy nuclei (e.g. C-shocks, UV fields, X-rays, cosmic rays) leave clear imprints in the chemistry of the gas, which allow to characterise the nucleus activity by its molecular abundances.
We surveyed the circumnuclear disk of the Seyfert galaxy NGC1068 between the frequencies 86.2 GHz and 115.6 GHz, and identified 17 different molecules. Using a time and depth dependent chemical model we reproduced the observational results, and show that the column densities of most of the species are better reproduced if the molecular gas is heavily pervaded by a high cosmic ray ionization rate of about 1000 times that of the Milky Way. We discuss how molecules in the NGC1068 nucleus may be influenced by this external radiation, as well as by UV radiation fields.
We aimed to study the chemistry of the circumnuclear molecular gas of NGC1068, and to compare it with those of the starburst galaxies M82 and NGC253. Using the IRAM-30m telescope, we observed the inner 2 kpc of NGC1068 between 86.2 GHz and 115.6 GHz. We identified 35 spectral features, corresponding to 24 different molecular species. Among them, HC3N, SO, N2H+, CH3CN, NS, 13CN, and HN13C are detected for the first time in NGC1068. Assuming local thermodynamic equilibrium (LTE), we calculated the column densities of the detected molecules, as well as the upper limits to the column densities of some undetected species. The comparison among the chemistries of NGC1068, M82, and NGC253, suggests that, apart from X-rays, shocks also determine the chemistry of NGC1068. We propose the column density ratio between CH3CCH and HC3N as a prime indicator of the imprints of starburst and AGN environments in the circumnuclear interstellar medium. This ratio is, at least, 64 times larger in M82 than in NGC1068, and, at least, 4 times larger in NGC253 than in NGC1068. Finally, we used the UCL_CHEM and UCL_PDR chemical codes to constrain the origin of the species, as well as to test the influence of UV radiation fields and cosmic rays on the observed abundances.
We aim to study the properties of the dense molecular gas towards the inner few 100 pc of four nearby starburst galaxies dominated both by photo dissociation regions (M82) and large-scale shocks (NGC253, IC342 and Maffei2), and to relate the chemical and physical properties of the molecular clouds with the evolutionary stage of the nuclear starbursts. We have carried out multi-transitional observations and analyses of three dense gas molecular tracers, CS, HC3N and CH3CCH, using Boltzmann diagrams in order to determine the rotational temperatures and column densities of the dense gas, and using a Large Velocity Gradients model to calculate the H2 density structure in the molecular clouds. The CS and HC3N data indicate the presence of density gradients in the molecular clouds, showing similar excitation conditions, and suggesting that they arise from the same gas components. In M82, CH3CCH has the highest fractional abundance determined in a extragalactic source (10^-8). The density and the chemical gradients found in all galaxies can be explained in the framework of the starburst evolution. The young shock-dominatedstarburst galaxies, like presumably Maffei2, show a cloud structure with a rather uniform density and chemical composition which suggests low star formation activity. Molecular clouds in galaxies with starburst in an intermediate stage of evolution, such as NGC253 and IC342, show clouds with a large density contrast (two orders of magnitude) between the denser regions (cores) and the less dense regions (halos) of the molecular clouds and relatively constant chemical abundance. Finally, the galaxy with the most evolved starburst, M82, has clouds with a rather uniform density structure, large envelopes of atomic/molecular gas subjected to UV photodissociating radiation from young star clusters, and very different chemical abundances of HC3N and CH3CCH.
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