Glycine (NH2CH2COOH) is the simplest amino acid relevant for life. Its detection in the interstellar medium is key to understand the formation mechanisms of pre-biotic molecules and their subsequent delivery onto planetary systems. Glycine has extens
ively been searched for toward hot molecular cores, although these studies did not yield any firm detection. In contrast to hot cores, low-mass star forming regions, and in particular their earliest stages represented by cold pre-stellar cores, may be better suited for the detection of glycine as well as more relevant for the study of pre-biotic chemistry in young Solar System analogs. We present 1D spherically symmetric radiative transfer calculations of the glycine emission expected to arise from the low-mass pre-stellar core L1544. Water vapour has recently been reported toward this core, indicating that a small fraction of the grain mantles in L1544 (~0.5%) has been injected into the gas phase. Assuming that glycine is photo-desorbed together with water in L1544, and considering a solid abundance of glycine on ices of ~1E-4 with respect to water, our calculations reveal that several glycine lines between 67 GHz and 80 GHz have peak intensities larger than 10 mK. These results show for the first time that glycine could reach detectable levels in cold objects such as L1544. This opens up the possibility to detect glycine, and other pre-biotic species, at the coldest and earliest stages in the formation of Solar-type systems with near-future instrumentation such as the Band 2 receivers of ALMA.
The Solar System formed about 4.6 billion years ago from a condensation of matter inside a molecular cloud. Trying to reconstruct what happened is the goal of this chapter. For that, we put together our understanding of Galactic objects that will eve
ntually form new suns and planetary systems, with our knowledge on comets, meteorites and small bodies of the Solar System today. Our specific tool is the molecular deuteration, namely the amount of deuterium with respect to hydrogen in molecules. This is the Ariadnes thread that helps us to find the way out from a labyrinth of possible histories of our Solar System. The chapter reviews the observations and theories of the deuterium fractionation in pre-stellar cores, protostars, protoplanetary disks, comets, interplanetary dust particles and meteorites and links them together trying to build up a coherent picture of the history of the Solar System formation. We emphasise the interdisciplinary nature of the chapter, which gathers together researchers from different communities with the common goal of understanding the Solar System history.
The enormous radiative and mechanical luminosities of massive stars impact a vast range of scales and processes, from the reionization of the universe, to the evolution of galaxies, to the regulation of the interstellar medium, to the formation of st
ar clusters, and even to the formation of planets around stars in such clusters. Two main classes of massive star formation theory are under active study, Core Accretion and Competitive Accretion. In Core Accretion, the initial conditions are self-gravitating, centrally concentrated cores that condense with a range of masses from the surrounding, fragmenting clump environment. They then undergo relatively ordered collapse via a central disk to form a single star or a small-N multiple. In this case, the pre-stellar core mass function has a similar form to the stellar initial mass function. In Competitive Accretion, the material that forms a massive star is drawn more chaotically from a wider region of the clump without passing through a phase of being in a massive, coherent core. In this case, massive star formation must proceed hand in hand with star cluster formation. If stellar densities become very high near the cluster center, then collisions between stars may also help to form the most massive stars. We review recent theoretical and observational progress towards understanding massive star formation, considering physical and chemical processes, comparisons with low and intermediate-mass stars, and connections to star cluster formation.
The deuterium fraction [N$_2$D$^+$]/[N$_2$H$^+$], may provide information about the ages of dense, cold gas structures, important to compare with dynamical models of cloud core formation and evolution. Here we introduce a complete chemical network wi
th species containing up to three atoms, with the exception of the Oxygen chemistry, where reactions involving H$_3$O$^+$ and its deuterated forms have been added, significantly improving the consistency with comprehensive chemical networks. Deuterium chemistry and spin states of H$_2$ and H$_3^+$ isotopologues are included in this primarily gas-phase chemical model. We investigate dependence of deuterium chemistry on model parameters: density ($n_{rm H}$), temperature, cosmic ray ionization rate, and gas-phase depletion factor of heavy elements ($f_{rm D}$). We also explore the effects of time-dependent freeze-out of gas-phase species and dynamical evolution of density at various rates relative to free-fall collapse. For a broad range of model parameters, the timescales to reach large values of $D_{rm frac}^{rm N_2H^+} gtrsim 0.1$, observed in some low- and high-mass starless cores, are relatively long compared to the local free-fall timescale. These conclusions are unaffected by introducing time-dependent freeze-out and considering models with evolving density, unless the initial $f_{rm D} gtrsim$ 10. For fiducial model parameters, achieving $D_{rm frac}^{rm N_2H^+} gtrsim 0.1$ requires collapse to be proceeding at rates at least several times slower than that of free-fall collapse, perhaps indicating a dynamically important role for magnetic fields in the support of starless cores and thus the regulation of star formation.
Our Sun and planetary system were born about 4.5 billion years ago. How did this happen and what is our heritage from these early times? This review tries to address these questions from an astrochemical point of view. On the one hand, we have some c
rucial information from meteorites, comets and other small bodies of the Solar System. On the other hand, we have the results of studies on the formation process of Sun-like stars in our Galaxy. These results tell us that Sun-like stars form in dense regions of molecular clouds and that three major steps are involved before the planet formation period. They are represented by the pre-stellar core, protostellar envelope and protoplanetary disk phases. Simultaneously with the evolution from one phase to the other, the chemical composition gains increasing complexity. In this review, we first present the information on the chemical composition of meteorites, comets and other small bodies of the Solar System, which is potentially linked to the first phases of the Solar Systems formation. Then we describe the observed chemical composition in the pre-stellar core, protostellar envelope and protoplanetary disk phases, including the processes that lead to them. Finally, we draw together pieces from the different objects and phases to understand whether and how much we inherited chemically from the time of the Suns birth.
Water is a crucial molecule in molecular astrophysics as it controls much of the gas/grain chemistry, including the formation and evolution of more complex organic molecules in ices. Pre-stellar cores provide the original reservoir of material from w
hich future planetary systems are built, but few observational constraints exist on the formation of water and its partitioning between gas and ice in the densest cores. Thanks to the high sensitivity of the Herschel Space Observatory, we report on the first detection of water vapor at high spectral resolution toward a dense cloud on the verge of star formation, the pre-stellar core L1544. The line shows an inverse P-Cygni profile, characteristic of gravitational contraction. To reproduce the observations, water vapor has to be present in the cold and dense central few thousand AU of L1544, where species heavier than Helium are expected to freeze-out onto dust grains, and the ortho:para H2 ratio has to be around 1:1 or larger. The observed amount of water vapor within the core (about 1.5x10^{-6} Msun) can be maintained by Far-UV photons locally produced by the impact of galactic cosmic rays with H2 molecules. Such FUV photons irradiate the icy mantles, liberating water wapor in the core center. Our Herschel data, combined with radiative transfer and chemical/dynamical models, shed light on the interplay between gas and solids in dense interstellar clouds and provide the first measurement of the water vapor abundance profile across the parent cloud of a future solar-type star and its potential planetary system.
H2D+ is a primary ion which dominates the gas-phase chemistry of cold dense gas. Therefore it is hailed as a unique tool in probing the earliest, prestellar phase of star formation. Observationally, its abundance and distribution is however just begi
nning to be understood in low-mass prestellar and cluster-forming cores. In high mass star forming regions, H2D+ has been detected only in two cores, and its spatial distribution remains unknown. Here we present the first map of the 372 GHz ortho-H2D+ and N2H+ 4-3 transition in the DR21 filament of Cygnus-X with the JCMT, and N2D+ 3--2 and dust continuum with the SMA. We have discovered five very extended (<= 34000 AU diameter) weak structures in H2D+ in the vicinity of, but distinctly offset from embedded protostars. More surprisingly, the H2D+ peak is not associated with either a dust continuum or N2D+ peak. We have therefore uncovered extended massive cold dense gas that was undetected with previous molecular line and dust continuum surveys of the region. This work also shows that our picture of the structure of cores is too simplistic for cluster forming cores and needs to be refined: neither dust continuum with existing capabilities, nor emission in tracers like N2D+ can provide a complete census of the total prestellar gas in such regions. Sensitive H2D+ mapping of the entire DR21 filament is likely to discover more of such cold quiescent gas reservoirs in an otherwise active high mass star-forming region.
We present high spatial (<300 AU) and spectral (0.07 km/s) resolution Submillimeter Array observations of the dense starless cluster core Oph A-N6, in the 1 mm dust continuum and the 3-2 line of N2H+ and N2D+. The dust continuum observations reveal a
compact source not seen in single-dish observations, of size ~1000 AU and mass 0.005-0.01 Modot. The combined line and single-dish observations reveal a core of size 3000 times 1400 AU elongated in a NW-SE direction, with almost no variation in either line width or line center velocity across the map, and very small non-thermal motions. The deuterium fraction has a peak value of ~0.15 and is >0.05 over much of the core. The N2H+ column density profile across the major axis of Oph A-N6 is well represented by an isothermal cylinder, with temperature 20 K, peak density 7.1 times 10^6 cm^{-3}, and N2H+ abundance 2.7 times 10^{-10}. The mass of Oph A-N6 is estimated to be 0.29 Modot, compared to a value of 0.18 Modot from the isothermal cylinder analysis, and 0.63 Modot for the critical mass for fragmentation of an isothermal cylinder. Compared to isolated low-mass cores, Oph A-N6 shows similar narrow line widths and small velocity variation, with a deuterium fraction similar to evolved dense cores. It is significantly smaller than isolated cores, with larger peak column and volume density. The available evidence suggests Oph A-N6 has formed through the fragmentation of the Oph A filament and is the precursor to a low-mass star. The dust continuum emission suggests it may already have begun to form a star.
Stars like our Sun and planets like our Earth form in dense regions within interstellar molecular clouds, called pre-stellar cores (PSCs). PSCs provide the initial conditions in the process of star and planet formation. In the past 15 years, detailed
observations of (low-mass) PSCs in nearby molecular cloud complexes have allowed us to find that they are cold (T < 10 K) and quiescent (molecular line widths are close to thermal), with a chemistry profoundly affected by molecular freeze-out onto dust grains. In these conditions, deuterated molecules flourish, becoming the best tools to unveil the PSC physical and chemical structure. Despite their apparent simplicity, PSCs still offer puzzles to solve and they are far from being completely understood. For example, what is happening to the gas and dust in their nuclei (the future stellar cradles) is still a mystery that awaits for ALMA. Other important questions are: how do different environments and external conditions affect the PSC physical/chemical structure? Are PSCs in high-mass star forming regions similar to the well-known low-mass PSCs? Here I review observational and theoretical work on PSCs in nearby molecular cloud complexes and the ongoing search and study of massive PSCs embedded in infrared dark clouds (IRDCs), which host the initial conditions for stellar cluster and high-mass star formation.
Excess levels of 15N isotopes which have been detected in primitive solar system materials are explained as a remnant of interstellar chemistry which took place in regions of the protosolar nebula. Chemical models of nitrogen fractionation in cold cl
ouds predict an enhancement in the gas-phase abundance of 15N-bearing molecules, thus we have searched for 15N variants of the N2H+ ion in L1544, which is one of the best candidate sources for detection owing to its low central core temperature and high CO depletion. With the IRAM 30m telescope we have obtained deep integrations of the N2H+(1-0) line at 91.2 GHz. The N2H+(1-0) line has been detected toward the dust emission peak of L1544. The 14N/15N abundance ratio in N2H+ resulted 446+/-71, very close to the protosolar value of ~450, higher than the terrestrial ratio of ~270, and significantly lower than the lower limit in L1544 found by Gerin et al. (2009, ApJ, 570, L101) in the same object using ammonia isotopologues.
