Weak ferrimagnetism and multiple magnetization reversal in {alpha}-Cr3(PO4)2

The chromium(II) orthophosphate {alpha}-Cr3(PO4)2 is a weak ferrimagnet with the Curie temperature TC = 29 K confirmed by a lambda-type peak in specific heat. Dominant antiferromagnetic interactions in this system are characterized by the Weiss temperature {Theta} = - 96 K, indicating an intermediate frustration ratio |{Theta}|/TC ~ 3. In its magnetically ordered states {alpha}-Cr3(PO4)2 exhibits a remarkable sequence of temperature-induced magnetization reversals sensitive to the protocol of measurements, i.e. either field-cooled or zero-field-cooled regimes. The reduction of the effective magnetic moment 4.5 {mu}B/Cr2+, as compared to the spin-only moment 4.9 {mu}B/Cr2+, cannot be ascribed to the occurence of the low-spin state in any crystallographic site of the Jahn-Teller active 3d4 Cr2+ ions. X-ray absorption spectra at the K-edge indicate divalent chromium and unravel the high-spin state of these ions at the L2,3-edges. Weak ferrimagnetism and multiple magnetization reversal phenomena seen in this compound could be ascribed to incomplete cancellation and distortion of partial spontaneous magnetization functions of Cr2+ in its six crystallographically inequivalent positions.