The present discussion rises a number of the questions. For example, is rotational coherence of large molecules necessarily destroyed in the conventionally statistical limit of structureless non-selective continuum (for fixed total spin and parity va
lues) under the conditions of complete intramolecular energy redistribution and vibrational dephasing in the regime of strong ro-vibrational coupling? For the slow cross-symmetry phase relaxation, quantum coherent superpositions of a large number of complex configurations with, e.g., many different total angular momenta produce image of a rotation of macroscopic object with classically fixed (single) total angular momentum. Suppose that the quantum coherent superpositions involving a very large number of different good quantum numbers play a role, in a hidden form, in a formation of macroscopic world. Then why these quantum superpositions are so stable against quick aging/decay of ordered complex structures preventing or slowing down tendencies towards uniform occupation of the available phase space as prescribed by the random matrix theory? And what kind of complex macroscopic phenomena may reveal traces of partially coherent quantum superpositions involving a huge number of quantum-mechanically different integrals of motion behind of what is referred to as conservation laws in classical physics employed for the description of the macroscopic world?
We shall use symmetry breaking as a tool to attack the problem of identifying the topology of chaotic scatteruing with more then two degrees of freedom. specifically we discuss the structure of the homoclinic/heteroclinic tangle and the connection be
tween the chaotic invariant set, the scattering functions and the singularities in the cross section for a class of scattering systems with one open and two closed degrees of freedom.
This article treats chaotic scattering with three degrees of freedom, where one of them is open and the other two are closed, as a first step toward a more general understanding of chaotic scattering in higher dimensions. Despite of the strong rest
rictions it breaks the essential simplicity implicit in any two-dimensional time-independent scattering problem. Introducing the third degree of freedom by breaking a continuous symmetry, we first explore the topological structure of the homoclinic/heteroclinic tangle and the structures in the scattering functions. Then we work out implications of these structures for the doubly differential cross section. The most prominent structures in the cross section are rainbow singularities. They form a fractal pattern which reflects the fractal structure of the chaotic invariant set. This allows to determine structures in the cross section from the invariant set and conversely, to obtain information about the topology of the invariant set from the cross section. The latter is a contribution to the inverse scattering problem for chaotic systems.
The phase--space volume of regions of regular or trapped motion, for bounded or scattering systems with two degrees of freedom respectively, displays universal properties. In particular, sudden reductions in the phase-space volume or gaps are observe
d at specific values of the parameter which tunes the dynamics; these locations are approximated by the stability resonances. The latter are defined by a resonant condition on the stability exponents of a central linearly stable periodic orbit. We show that, for more than two degrees of freedom, these resonances can be excited opening up gaps, which effectively separate and reduce the regions of trapped motion in phase space. Using the scattering approach to narrow rings and a billiard system as example, we demonstrate that this mechanism yields rings with two or more components. Arcs are also obtained, specifically when an additional (mean-motion) resonance condition is met. We obtain a complete representation of the phase-space volume occupied by the regions of trapped motion.
