We present high spectral resolution (~3 km/s) observations of the nu_2 ro-vibrational band of H2O in the 6.086--6.135 micron range toward the massive protostar AFGL 2591 using the Echelon-Cross-Echelle Spectrograph (EXES) on the Stratospheric Observa
tory for Infrared Astronomy (SOFIA). Ten absorption features are detected in total, with seven caused by transitions in the nu_2 band of H2O, two by transitions in the first vibrationally excited nu_2 band of H2O, and one by a transition in the nu_2 band of H2{18}O. Among the detected transitions is the nu_2 1(1,1)--0(0,0) line which probes the lowest lying rotational level of para-H2O. The stronger transitions appear to be optically thick, but reach maximum absorption at a depth of about 25%, suggesting that the background source is only partially covered by the absorbing gas, or that the absorption arises within the 6 micron emitting photosphere. Assuming a covering fraction of 25%, the H2O column density and rotational temperature that best fit the observed absorption lines are N(H2O)=(1.3+-0.3)*10^{19} cm^{-2} and T=640+-80 K.
In diffuse interstellar clouds the chemistry that leads to the formation of the oxygen bearing ions OH+, H2O+, and H3O+ begins with the ionization of atomic hydrogen by cosmic rays, and continues through subsequent hydrogen abstraction reactions invo
lving H2. Given these reaction pathways, the observed abundances of these molecules are useful in constraining both the total cosmic-ray ionization rate of atomic hydrogen (zeta_H) and molecular hydrogen fraction, f(H2). We present observations targeting transitions of OH+, H2O+, and H3O+ made with the Herschel Space Observatory along 20 Galactic sight lines toward bright submillimeter continuum sources. Both OH+ and H2O+ are detected in absorption in multiple velocity components along every sight line, but H3O+ is only detected along 7 sight lines. From the molecular abundances we compute f(H2) in multiple distinct components along each line of sight, and find a Gaussian distribution with mean and standard deviation 0.042+-0.018. This confirms previous findings that OH+ and H2O+ primarily reside in gas with low H2 fractions. We also infer zeta_H throughout our sample, and find a log-normal distribution with mean log(zeta_H)=-15.75, (zeta_H=1.78x10^-16 s^-1), and standard deviation 0.29 for gas within the Galactic disk, but outside of the Galactic center. This is in good agreement with the mean and distribution of cosmic-ray ionization rates previously inferred from H3+ observations. Ionization rates in the Galactic center tend to be 10--100 times larger than found in the Galactic disk, also in accord with prior studies.
We have obtained improved spectra of key fundamental band lines of H3+, R(1,1)l, R(3,3)l, and R(2,2)l, and ro-vibrational transitions of CO on sightlines toward the luminous infrared sources GCIRS 3 and GCIRS 1W, each located in the Central Cluster o
f the Galactic center within several arcseconds of Sgr A*. The spectra reveal absorption occurring in three kinds of gaseous environments: (1) cold dense and diffuse gas associated with foreground spiral/lateral arms; (2) warm and diffuse gas absorbing over a wide and mostly negative velocity range, which appears to fill a significant fraction of the Galaxys Central Molecular Zone (CMZ); and (3) warm, dense and compact clouds with velocities near +50 km s^-1 probably within 1-2 pc of the center. The absorptions by the first two cloud types are nearly identical for all the sources in the Central Cluster, and are similar to those previously observed on sightlines from Sgr A* to 30 pc east of it. Cloud type (3), which has only been observed toward the Central Cluster, shows distinct differences between the sightlines to GCIRS 3 and GCIRS 1W, which are separated on the sky by only 0.33 pc in projection. We identify this material as part of an inward extension of the Circumnuclear Disk previously known from HCN mapping. Lower limits on the products of the hydrogen ionization rate zeta and the path length L are 2.3 x 10^5 cm s^-1 and 1.5 x 10^3 cm s^-1 for the warm and diffuse CMZ gas and for the warm and dense clouds in the core, respectively. The limits indicate that the ionization rates in these regions are well above 10^-15 s^-1.
We report observations and analysis of infrared spectra of H3+ and CO lines in the Galactic center, within a few parsecs of the central black hole, Sgr A*. We find a cosmic ray ionization rate typically an order of magnitude higher than outside the G
alactic center. Notwithstanding, the elevated cosmic ray ionization rate is 4 orders of magnitude too short to match the proton energy spectrum as inferred from the recent discovery of the TeV gamma-ray source in the vicinity of Sgr A*.
