We present extensive calculations of radiative transition rates and electron impact collision strengths for Fe II. The data sets involve 52 levels from the $3d,^7$, $3d,^64s$, and $3d,^54s^2$ configurations. Computations of $A$-values are carried out
with a combination of state-of-the-art multiconfiguration approaches, namely the relativistic Hartree--Fock, Thomas--Fermi--Dirac potential, and Dirac--Fock methods; while the $R$-matrix plus intermediate coupling frame transformation, Breit--Pauli $R$-matrix and Dirac $R$-matrix packages are used to obtain collision strengths. We examine the advantages and shortcomings of each of these methods, and estimate rate uncertainties from the resulting data dispersion. We proceed to construct excitation balance spectral models, and compare the predictions from each data set with observed spectra from various astronomical objects. We are thus able to establish benchmarks in the spectral modeling of [Fe II] emission in the IR and optical regions as well as in the UV Fe II absorption spectra. Finally, we provide diagnostic line ratios and line emissivities for emission spectroscopy as well as column densities for absorption spectroscopy. All atomic data and models are available online and through the AtomPy atomic data curation environment.
We present a method for computing uncertainties in spectral models, i.e. level populations, line emissivities, and emission line ratios, based upon the propagation of uncertainties originating from atomic data. We provide analytic expressions, in the
form of linear sets of algebraic equations, for the coupled uncertainties among all levels. These equations can be solved efficiently for any set of physical conditions and uncertainties in the atomic data. We illustrate our method applied to spectral models of O III and Fe II and discuss the impact of the uncertainties on atomic systems under different physical conditions. As to intrinsic uncertainties in theoretical atomic data, we propose that these uncertainties can be estimated from the dispersion in the results from various independent calculations. This technique provides excellent results for the uncertainties in A-values of forbidden transitions in [Fe II].
We present a detailed analysis of the Astrophysical Research Consortium 3.5 m telescope spectrum of QSO SDSS J0838+2955. The object shows three broad absorption line (BAL) systems at 22,000, 13,000, and 4900 km s^-1 blueshifted from the systemic reds
hift of z=2.043. Of particular interest is the lowest velocity system that displays absorption from low-ionization species such as Mg II, Al II, Si II, Si II*, Fe II and Fe II*. Accurate column densities were measured for all transitions in this lowest velocity BAL using an inhomogeneous absorber model. The ratio of column densities of Si II* and Fe II* with respect to their ground states gave an electron number density of log n_e (cm^-3) = 3.75 +/- 0.22 for the outflow. Photoionization modeling with careful regards to chemical abundances and the incident spectral energy distribution predicts an ionization parameter of log U_H = -1.93 +/- 0.21 and a hydrogen column density of log N_H (cm^-2) = 20.80 +/- 0.28. This places the outflow at 3.3+1.5-1.0 kpc from the central AGN. Assuming that the fraction of solid angle subtended by the outflow is 0.2, these values yield a kinetic luminosity of (4.5+3.1-1.8) x 10^45 erg s^-1, which is (1.4+1.1-0.6)% the bolometric luminosity of the QSO itself. Such large kinetic luminosity suggests that QSO outflows are a major contributor to AGN feedback mechanisms.
