We derive the dense core structure and the water abundance in four massive star-forming regions which may help understand the earliest stages of massive star formation. We present Herschel-HIFI observations of the para-H2O 1_11-0_00 and 2_02-1_11 and
the para-H2-18O 1_11-0_00 transitions. The envelope contribution to the line profiles is separated from contributions by outflows and foreground clouds. The envelope contribution is modelled using Monte-Carlo radiative transfer codes for dust and molecular lines (MC3D and RATRAN), with the water abundance and the turbulent velocity width as free parameters. While the outflows are mostly seen in emission in high-J lines, envelopes are seen in absorption in ground-state lines, which are almost saturated. The derived water abundances range from 5E-10 to 4E-8 in the outer envelopes. We detect cold clouds surrounding the protostar envelope, thanks to the very high quality of the Herschel-HIFI data and the unique ability of water to probe them. Several foreground clouds are also detected along the line of sight. The low H2O abundances in massive dense cores are in accordance with the expectation that high densities and low temperatures lead to freeze-out of water on dust grains. The spread in abundance values is not clearly linked to physical properties of the sources.
Context. Water together with O2 are important gas phase ingredients to cool dense gas in order to form stars. On dust grains, H2 O is an important constituent of the icy mantle in which a complex chemistry is taking place, as revealed by hot core obs
ervations. The formation of water can occur on dust grain surfaces, and can impact gas phase composition. Aims. The formation of molecules such as OH, H2 O, HO2, H2 O2, as well as their deuterated forms and O2 and O3 is studied in order to assess how the chemistry varies in different astrophysical environments, and how the gas phase is affected by grain surface chemistry. Methods. We use Monte Carlo simulations to follow the formation of molecules on bare grains as well as the fraction of molecules released into the gas phase. We consider a surface reaction network, based on gas phase reactions, as well as UV photo-dissociation of the chemical species. Results. We show that grain surface chemistry has a strong impact on gas phase chemistry, and that this chemistry is very different for different dust grain temperatures. Low temperatures favor hydrogenation, while higher temperatures favor oxygenation. Also, UV photons dissociate the molecules on the surface, that can reform subsequently. The formation-destruction cycle increases the amount of species released into the gas phase. We also determine the time scales to form ices in diffuse and dense clouds, and show that ices are formed only in shielded environments, as supported by observations.
The study of physical and chemical properties of massive protostars is critical to better understand the evolutionary sequence which leads to the formation of high-mass stars. IRAS 18151-1208 is a nearby massive region (d = 3kpc, L ~ 20000 Lsun) whic
h splits into three cores: MM1, MM2 and MM3 (separated by 1-2). We aim at (1) studying the physical and chemical properties of the individual MM1, MM2 and MM3 cores; (2) deriving their evolutionary stages; (3) using these results to improve our view of the evolutionary sequence of massive cores. The region was observed in the CS, C34S, H2CO, HCO+, H13CO+, and N2H+ lines at mm wavelengths with the IRAM 30m and Mopra telescopes. We use 1D and 2D modeling of the dust continuum to derive the density and temperature distributions, which are then used in the RATRAN code to model the lines and constrain the abundances of the observed species. All the lines were detected in MM1 and MM2. MM3 shows weaker emission, or even is undetected in HCO+ and all isotopic species. MM2 is driving a newly discovered CO outflow and hosts a mid-IR-quiet massive protostar. The abundance of CS is significantly larger in MM1 than in MM2, but smaller than in a reference massive protostar such as AFGL2591. In contrast the N2H+ abundance decreases from MM2 to MM1, and is larger than in AFGL2591. Both MM1 and MM2 host an early phase massive protostar, but MM2 (and mid-IR-quiet sources in general) is younger and more dominated by the host protostar than MM1 (mid-IR-bright). The MM3 core is probably in a pre-stellar phase. We find that the N2H+/C34S ratio varies systematically with age in the massive protostars for which the data are available. It can be used to identify young massive protostars.
