We present high spectral resolution mid-IR observations of SiS towards the C-rich AGB star IRC+10216 carried out with the Texas Echelon-cross-Echelle Spectrograph mounted on the NASA Infrared Telescope Facility. We have identified 204 ro-vibrational
lines of 28Si32S, 26 of 29Si32S, 20 of 28Si34S, and 15 of 30Si32S in the frequency range 720-790 cm-1. These lines belong to bands v=1-0, 2-1, 3-2, 4-3, and 5-4, and involve rotational levels with Jlow<90. About 30 per cent of these lines are unblended or weakly blended and can be partially or entirely fitted with a code developed to model the mid-IR emission of a spherically symmetric circumstellar envelope composed of expanding gas and dust. The observed lines trace the envelope at distances to the star <35R* (~0.7 arcsec). The fits are compatible with an expansion velocity of 1+2.5(r/R*-1) km/s between 1 and 5R*, 11 km/s between 5 and 20R*, and 14.5 km/s outwards. The derived abundance profile of 28Si32S with respect to H2 is 4.9e-6 between the stellar photosphere and 5R*, decreasing linearly to 1.6e-6 at 20R* and to 1.3e-6 at 50R*. 28Si32S seems to be rotationally under LTE in the region of the envelope probed with our observations and vibrationally out of LTE in most of it. There is a red-shifted emission excess in the 28Si32S lines of band v=1-0 that cannot be found in the lines of bands v=2-1, 3-2, 4-3, and 5-4. This excess could be explained by an enhancement of the vibrational temperature around 20R* behind the star. The derived isotopic ratios 28Si/29Si, and 32S/34S are 17 and 14, compatible with previous estimates.
The physical structures of the outer atmospheres of red giants are not known. They are certainly complex and a range of recent observations are showing that we need to embrace to non-classical atmosphere models to interpret these regions. This region
s properties is of importance, not the least, for the understanding of the mass-loss mechanism for these stars, which is not still understood. Here, we present observational constraints of the outer regions of red giants, based on mid-IR, high spectral resolution spectra. We also discuss possible non-LTE effects and highlight a new non-LTE code that will be used to analyse the spectra of these atmospheric layers. We conclude by mentioning our new SOFIA/EXES observations of red giants at 6 microns, where the vibration-rotation lines of water vapour can be detected and spectrally resolved for the first time.
We present a mid-infrared high spectral resolution spectrum of CRL618 in the frequency ranges 778-784 and 1227-1249 cm^-1 (8.01-8.15 and 12.75-12.85 um) taken with the Texas Echelon-cross-Echelle Spectrograph (TEXES) and the Infrared Telescope Facili
ty (IRTF). We have identified more than 170 ro-vibrational lines arising from C2H2, HCN, C4H2, and C6H2. We have found no unmistakable trace of C8H2. The line profiles display a complex structure suggesting the presence of polyacetylenes in several components of the circumstellar envelope (CSE). We derive total column densities of 2.5 10^17, 3.1 10^17, 2.1 10^17, 9.3 10^16 cm^-2, and < 5 10^16 cm^-2 for HCN, C2H2, C4H2, C6H2, and C8H2, respectively. The observations indicate that both the rotational and vibrational temperatures in the innermost CSE depend on the molecule, varying from 100 to 350 K for the rotational temperatures and 100 to 500 K for the vibrational temperatures. Our results support a chemistry in the innermost CSE based on radical-neutral reactions triggered by the intense UV radiation field.
We present high resolution (R = 90,000) mid-infrared spectra of M dwarfs. The mid infrared region of the spectra of cool low mass stars contain pure rotational water vapour transitions that may provide us with a new methodology in the determination o
f the effective temperatures for low mass stars. We identify and assign water transitions in these spectra and determine how sensitive each pure rotational water transition is to small (25 K) changes in effective temperature. We find that, of the 36 confirmed and assigned pure rotational water transitions, at least 10 should be sensitive enough to be used as temperature indicators.
A spectral survey of IRC+10216 has been carried out in the range 11 to 14 um with a spectral resolution of about 4 km s^-1. We have identified a forest of lines in six bands of C2H2 involving the vibrational states from the ground to 3nu5 and in two
bands of HCN, involving the vibrational states from the ground up to 2nu2. Some of these transitions are observed also in H13CCH and H13CN. We have estimated the kinetic, vibrational, and rotational temperatures, and the abundances and column densities of C2H2 and HCN between 1 and 300 R* (1.5E16 cm) by fitting about 300 of these ro-vibrational lines. The envelope can be divided into three regions with approximate boundaries at 0.019 arcsec (the stellar photosphere), 0.1 arcsec (the inner dust formation zone), and 0.4 arcsec (outer dust formation zone). Most of the lines might require a large microturbulence broadening. The derived abundances of C2H2 and HCN increase by factors of 10 and 4, respectively, from the innermost envelope outwards. The derived column densities for both C2H2 and HCN are 1.6E19 cm^-2. Vibrational states up to 3000 K above ground are populated, suggesting pumping by near-infrared radiation from the star and innermost envelope. Low rotational levels can be considered under LTE while those with J>20-30 are not thermalized. A few lines require special analysis to deal with effects like overlap with lines of other molecules.
