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FeGa$_3$ is an unusual intermetallic semiconductor that presents intriguing magnetic responses to the tuning of its electronic properties. When doped with Ge, the system evolves from diamagnetic to paramagnetic to ferromagnetic ground states that are not well understood. In this work, we have performed a joint theoretical and experimental study of FeGa$_{3-x}$Ge$_x$ using Density Functional Theory and magnetic susceptibility measurements. For low Ge concentrations we observe the formation of localized moments on some Fe atoms and, as the dopant concentration increases, a more delocalized magnetic behavior emerges. The magnetic configuration strongly depends on the dopant distribution, leading even to the appearance of antiferromagnetic interactions in certain configurations.
Granular fronts are a common yet unexplained phenomenon emerging during the gravity driven free-surface flow of concentrated suspensions. They are usually believed to be the result of fluid convection in combination with particle size segregation. Ho wever, suspensions composed of uniformly sized particles also develop a granular front. Within a large rotating drum, a stationary recirculating avalanche is generated. The flowing material is a mixture of a visco-plastic fluid obtained from a kaolin-water dispersion, with spherical ceramic particles denser than the fluid. The goal is to mimic the composition of many common granular-fluid materials, like fresh concrete or debris flow. In these materials, granular and fluid phases have the natural tendency to segregate due to particle settling. However, through the shearing caused by the rotation of the drum, a reorganization of the phases is induced, leading to the formation of a granular front. By tuning the material properties and the drum velocity, it is possible to control this phenomenon. The setting is reproduced in a numerical environment, where the fluid is solved by a Lattice-Boltzmann Method, and the particles are explicitly represented using the Discrete Element Method. The simulations confirm the findings of the experiments, and provide insight into the internal mechanisms. Comparing the time-scale of particle settling with the one of particle recirculation, a non-dimensional number is defined, and is found to be effective in predicting the formation of a granular front.
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