Taking into account the phase fraction during transition for the first-order magnetocaloric materials, an improved isothermal entropy change determination has been put forward based on the Clausius-Clapeyron (CC) equation. It was found that the isoth
ermal entropy change value evaluated by our method is in excellent agreement with those determined from the Maxwell-relation (MR) for Ni-Mn-Sn Heusler alloys, which usually presents a weak field-induced phase transforming behavior. In comparison with MR, this method could give rise to a favorable result derived from few thermomagnetic measurements. More importantly, we can eliminate the isothermal entropy change overestimation derived from MR, which always exists in the cases of Ni-Co-Mn-In and MnAs systems with a prominent field-induced transition. These results confirmed that such a CC-equation-based method is quite practical and superior to the MR-based ones in eliminating the spurious spike and reducing measuring cost.
Based on a minimal two-orbital model [Tai {it et al.}, Europhys. Lett. textbf{103}, 67001 (2013)], which captures the canonical electron-hole-doping phase diagram of the iron-pnictide BaFe$_{2}$As$_{2}$, we study the evolution of quasiparticle states
as a function of doping using the Bogoliubov-de Gennes equations with and without a single impurity. Analyzing the density of states of uniformly doped samples, we are able to identify the origin of the two superconducting gaps observed in optimally hole- or electron-doped systems. The local density of states (LDOS) is then examined near a single impurity in samples without antiferromagnetic order. The qualitative features of our results near the single impurity are consistent with a work based on a five-orbital model[K. Toshikaze {it et al.}, J. Phys. Soc. Jpn. textbf{79}, 083704 (2010)]. This further supports the validity of our two-orbital model in dealing with LDOS in the single-impurity problem. Finally, we investigate the evolution of the LDOS with doping near a single impurity in the unitary or strong scattering limit, such as Zn replacing Fe. The positions of the ingap resonance peaks exhibited in our LDOS may indirectly reflect the evolution of the Fermi surface topology according to the phase diagram. Our prediction of ingap states and the evolution of the LDOS near a strong scattering single impurity can be validated by experiments probing the local quasiparticle spectrum.
Based on the minimum two-orbital model and the phase diagram recently proposed by Tai et al. (Europhys. Lett. textbf{103}, 67001(2013)) for both electron- and hole-doped 122 iron-based superconducting compounds, we use the Bogoliubov-de Gennes equati
ons to perform a comprehensive investigation of the evolution of the Fermi surface (FS) topology in the presence of the collinear spin-density-wave (SDW) order as the doping is changed. In the parent compound, the ground state is the SDW order, where the FS is not completely gapped, and two types of Dirac cones, one electron-doped and the other hole-doped emerge in the magnetic Brillouin zone. Our findings are qualitatively consistent with recent angle-resolved photoemission spectroscopy and magneto-resistivity measurements. We also examine the FS evolution of both electron- and hole-doped cases and compare them with measurements, as well as with those obtained by other model Hamiltonians.
