We present the high resolution spectroscopic study of five -3.9<=[Fe/H]<=-2.5 stars in the Local Group dwarf spheroidal, Sculptor, thereby doubling the number of stars with comparable observations in this metallicity range. We carry out a detailed an
alysis of the chemical abundances of alpha, iron peak, light and heavy elements, and draw comparisons with the Milky Way halo and the ultra faint dwarf stellar populations. We show that the bulk of the Sculptor metal-poor stars follows the same trends in abundance ratios versus metallicity as the Milky Way stars. This suggests similar early conditions of star formation and a high degree of homogeneity of the interstellar medium. We find an outlier to this main regime, which seems to miss the products of the most massive of the TypeII supernovae. In addition to its value to help refining galaxy formation models, this star provides clues to the production of cobalt and zinc. Two of our sample stars have low odd-to-even barium isotope abundance ratios, suggestive of a fair proportion of s-process; we discuss the implication for the nucleosynthetic origin of the neutron capture elements.
We present atmospheric parameters for 51 nearby FG dwarfs uniformly distributed over the -2.60 < [Fe/H] < +0.20 metallicity range that is suitable for the Galactic chemical evolution research. Lines of iron, Fe I and Fe II, were used to derive a homo
geneous set of effective temperatures, surface gravities, iron abundances, and microturbulence velocities. We used high-resolution (R>60000) Shane/Hamilton and CFHT/ESPaDOnS observed spectra and non-local thermodynamic equilibrium (NLTE) line formation for Fe I and Fe II in the classical 1D model atmospheres. The spectroscopic method was tested with the 20 benchmark stars, for which there are multiple measurements of the infrared flux method (IRFM) Teff and their Hipparcos parallax error is < 10%. We found NLTE abundances from lines of Fe I and Fe II to be consistent within 0.06 dex for every benchmark star, when applying a scaling factor of S_H = 0.5 to the Drawinian rates of inelastic Fe+H collisions. The obtained atmospheric parameters were checked for each program star by comparing its position in the log g-Teff plane with the theoretical evolutionary track in the Yi et al. (2004) grid. Our final effective temperatures lie in between the T_IRFM scales of Alonso et al. (1996) and Casagrande et al. (2011), with a mean difference of +46 K and -51 K, respectively. NLTE leads to higher surface gravity compared with that for LTE. The shift in log g is smaller than 0.1 dex for stars with either [Fe/H] > -0.75, or Teff < 5750 K, or log g > 4.20. NLTE analysis is crucial for the VMP turn-off and subgiant stars, for which the shift in log g between NLTE and LTE can be up to 0.5 dex. The obtained atmospheric parameters will be used in the forthcoming papers to determine NLTE abundances of important astrophysical elements from lithium to europium and to improve observational constraints on the chemo-dynamical models of the Galaxy evolution.
Context. Synthetic model atmosphere calculations are still the most commonly used tool when determining precise stellar parameters and stellar chemical compositions. Besides three-dimensional models that consistently solve for hydrodynamic processes,
one-dimensional models that use an approximation for convective energy transport play the major role. Aims. We use modern Balmer-line formation theory as well as spectral energy distribution (SED) measurements for the Sun and Procyon to calibrate the model parameter {alpha} that describes the efficiency of convection in our 1D models. Convection was calibrated over a significant range in parameter space, reaching from F-K along the main sequence and sampling the turnoff and giant branch over a wide range of metallicities. This calibration was compared to theoretical evaluations and allowed an accurate modeling of stellar atmospheres. Methods. We used Balmer-line fitting and SED fits to determine the convective efficiency parameter {alpha}. Both methods are sensitive to the structure and temperature stratification of the deeper photosphere. Results. While SED fits do not allow a precise determination of the convective parameter for the Sun and Procyon, they both favor values significantly higher than 1.0. Balmer-line fitting, which we find to be more sensitive, suggests that the convective efficiency parameter {alpha} is $approx$ 2.0 for the main sequence and quickly decreases to $approx$ 1.0 for evolved stars. These results are highly consistent with predictions from 3D models. While the values on the main sequence fit predictions very well, measurements suggest that the decrease of convective efficiency as stars evolve to the giant branch is more dramatic than predicted by models.
Aims. The statistical equilibrium of neutral and ionized silicon in the atmospheres of metal-poor stars is discussed. Non-local thermodynamic equilibrium effects are investigated and the silicon abundances in metal-poor stars determined. Methods. We
have used high resolution, high signal to noise ratio spectra from the UVES spectragraph at the ESO VLT telescope. Line formation calculations of Si i and Si ii in the atmospheres of metal-poor stars are presented for atomic models of silicon including 174 terms and 1132 line transitions. Recent improved calculations of Si i and Si ii photoionization cross-sections are taken into account, and the influence of the free-free quasi-molecular absorption in the Ly alpha wing is investigated by comparing theoretical and observed fluxes of metal-poor stars. All abundance results are derived from LTE and NLTE statistical equilibrium calculations and spectrum synthesis methods. Results. It is found that the extreme ultraviolet radiation is very important for metal-poor stars, especially for the high temperature, very metal-poor stars. The radiative bound-free cross-sections also play a very important role for these stars. Conclusions. NLTE effects for Si are found to be important for metal-poor stars, in particular for warm metal-poor stars. It is found that these effects depend on the temperature. For warm metal-poor stars, the NLTE abundance correction reaches ~ 0.2 dex relative to standard LTE calculations. Our results indicate that Si is overabundant for metal-poor stars.
Non-LTE line formation for Pr II and Pr III is considered through a range of effective temperatures between 7250 K and 9500 K. A comprehensive model atom for Pr II/III is based on the measured and the predicted energy levels, in total, 6708 levels of
Pr II and Pr III. We describe calculations of the Pr II energy levels and oscillator strengths for the transitions in Pr II and Pr III. The influence of departures from LTE on Pr abundance determinations is evaluated. At Teff >= 8000 K departures from LTE lead to overionization of Pr II and to systematically depleted total absorption in the line and positive abundance corrections. At the lower temperatures, different lines of Pr II may be either weakened or amplified depending on the line strength. The non-LTE effects strengthen the Pr III lines and lead to negative abundance corrections. Non-LTE corrections grow with effective temperature for the Pr II lines, and, in contrast, they decline for the Pr III lines. The Pr II/III model atom is applied to determine the Pr abundance in the atmosphere of the roAp star HD 24712 from the lines of two ionization stages. In the chemically uniform atmosphere with [Pr/H] = 3, the departures from LTE may explain only small part (0.3 dex) of the difference between the LTE abundances derived from the Pr II and Pr III lines (2 dex). We find that the lines of both ionization stages are described for the vertical distribution of the praseodymium where the Pr enriched layer with [Pr/H] > 4 exists in the outer atmosphere at log tau_5000 < -4. The departures from LTE for Pr II/III are strong in the stratified atmosphere and have the opposite sign for the Pr II and Pr III lines. Using the revised partition function of Pr II and experimental transition probabilities, we determine the solar non-LTE abundance of Pr as log (Pr/H) = -11.15pm0.08.
Stellar parameters and abundances of Na, Mg, Al, K, Ca, Sr, Ba, and Eu are determined for four very metal-poor stars (-2.66 < [Fe/H] < -2.15) based on non-LTE line formation and analysis of high-resolution (R ~60000 and 90000) high signal-to-noise (S
/N > 200) observed spectra. A model atom for H I is presented. An effective temperature was obtained from the Balmer Halpha and Hbeta line wing fits, the surface gravity from the Hipparcos parallax if available and the non-LTE ionization balance between Ca I and Ca II. Based on the hyperfine structure affecting the Ba II resonance line, the fractional abundance of the odd isotopes of Ba was derived for HD 84937 and HD 122563 from a requirement that Ba abundances from the resonance line and subordinate lines of Ba II must be equal. For each star, non-LTE leads to a consistency of Teff from two Balmer lines and to a higher temperature compared to the LTE case, by up to 60 K. Non-LTE effects are important in spectroscopic determination of surface gravity from Ca I/Ca II. For each star with a known trigonometric gravity, non-LTE abundances from the lines of two ionization stages agree within the error bars, while a difference in the LTE abundances consists of 0.23 dex to 0.40 dex for different stars. Departures from LTE are found to be significant for the investigated atoms, and they strongly depend on stellar parameters. For HD 84937, the Eu/Ba ratio is consistent with the relative solar system r-process abundances, and the fraction of the odd isotopes of Ba, f_odd, equals 0.43+-0.14. The latter can serve as a constraint on r-process models. The lower Eu/Ba ratio and f_odd = 0.22+-0.15 found for HD 122563 suggest that the s-process or the unknown process has contributed significantly to the Ba abundance in this star.
