(Sr,Na)(Zn,Mn)2As2: A new diluted ferromagnetic semiconductor with the hexagonal CaAl2Si2 type structure

A new diluted ferromagnetic semiconductor (Sr,Na)(Zn,Mn)2As2 is reported, in which charge and spin doping are decoupled via Sr/Na and Zn/Mn substitutions, respectively, being distinguished from classic (Ga,Mn)As where charge & spin doping are simultaneously integrated. Different from the recently reported ferromagnetic (Ba,K)(Zn,Mn)2As2, this material crystallizes into the hexagonal CaAl2Si2-type structure. Ferromagnetism with a Curie temperature up to 20 K has been observed from magnetization. The muon spin relaxation measurements suggest that the exchange interaction between Mn moments of this new system could be different to the earlier DMS systems. This system provides an important means for studying ferromagnetism in diluted magnetic semiconductors.

(Ca,Na)(Zn,Mn)2As2: a new spin & charge doping decoupled diluted ferromagnetic semiconductor with hexagonal CaAl2Si2 structure

Here we report the successful synthesis of a spin- & charge-decoupled diluted magnetic semiconductor (Ca,Na)(Zn,Mn)2As2, crystallizing into the hexagonal CaAl2Si2 structure. The compound shows a ferromagnetic transition with a Curie temperature up to 33 K with 10% Na doping, which gives rise to carrier density of np~10^20 cm^-3. The new DMS is a soft magnetic material with HC<400 Oe. The anomalous Hall effect is observed below the ferromagnetic ordering temperature. With increasing Mn doping, ferromagnetic order is accompanied by an interaction between the local spin and mobile charge, giving rise to a minimum in resistivity at low temperatures and localizing the conduction electrons. The system provides an ideal platform for studying the interaction of the local spins and conduction electrons.

Photoemission and X-ray Absorption Studies of the Diluted Magnetic Semiconductor Ba$_{1-y}$K$_{y}$(Zn$_{1-x}$Mn$_{x}$)$_{2}$As$_{2}$ Isostructural to Fe-based Superconductors

The electronic and magnetic properties of a new diluted magnetic semiconductor (DMS) Ba$_{1-x}$K$_{x}$(Zn$_{1-y}$Mn$_{y}$)$_{2}$As$_{2}$, which is isostructural to so-called 122-type Fe-based superconductors, are investigated by x-ray absorption spectroscopy (XAS) and resonance photoemission spectroscopy (RPES). Mn $L_{2,3}$-edge XAS indicates that the doped Mn atoms have the valence 2+ and strongly hybridize with the $4p$ orbitals of the tetrahedrally coordinating As ligands. The Mn $3d$ partial density of states (PDOS) obtained by RPES shows a peak around 4 eV and relatively high between 0-2 eV below the Fermi level ($E_{F}$) with little contribution at $E_{F}$, similar to that of the archetypal DMS Ga$_{1-x}$Mn$_{x}$As. This energy level creates $d^{5}$ electron configuration with $S=5/2$ local magnetic moments at the Mn atoms. Hole carriers induced by K substitution for Ba atoms go into the top of the As $4p$ valence band and are weakly bound to the Mn local spins. The ferromagnetic correlation between the local spins mediated by the hole carriers induces ferromagnetism in Ba$_{1-x}$K$_{x}$(Zn$_{1-y}$Mn$_{y}$)$_{2}$As$_{2}$

Specific Heat of Ca0.33Na0.67Fe2As2

The specific heat of single crystal hole-doped Ca0.33Na0.67Fe2As2, Tc(onset)=33.7 K, was measured from 0.4 to 40 K. The discontinuity in the specific heat at Tc, deltaC, divided by Tc is 105 +- 5 mJ/molK2, consistent with values found previously for hole-doped Ba0.6K0.4Fe2As2 and somewhat above the general trend for deltaC/Tc vs Tc for the iron based superconductors established by Budko, Ni and Canfield. The usefulness of measured valued of deltaC/Tc as an important metric for the quality of samples is discussed.

New Diluted ferromagnetic semiconductor Li(Zn,Mn)P with decoupled charge and spin doping

We report the discovery of a new diluted magnetic semiconductor, Li(Zn,Mn)P, in which charge and spin are introduced independently via lithium off-stoichiometry and the isovalent substitution of Mn2+ for Zn2+, respectively. Isostructural to (Ga,Mn)As, Li(Zn,Mn)P was found to be a p-type ferromagnetic semiconductor with excess Lithium providing charge doping. First principles calculations indicate that excess Li is favored to partially occupy the Zn site, leading to hole doping. Ferromagnetism is mediated in semiconducting samples of relative low mobile carriers with a small coercive force, indicating an easy spin flip.

72 DA White Dwarfs Identified in LAMOST Pilot Survey

We present a spectroscopically identified catalogue of 72 DA white dwarfs from the LAMOST pilot survey. 35 are found to be new identifications after cross-correlation with the Eisenstein et al. and Villanova catalogues. The effective temperature and gravity of these white dwarfs are estimated by Balmer lines fitting. Most of them are hot white dwarfs. The cooling times and masses of these white dwarfs are estimated by interpolation in theoretical evolution tracks. The peak of mass distribution is found to be $sim$ 0.6 $M_odot$ which is consistent with prior work in the literature. The distances of these white dwarfs are estimated using the method of Synthetic Spectral Distances. All of these WDs are found to be in the Galactic disk from our analysis of space motions. Our sample supports the expectation white dwarfs with high mass are concentrated near the plane of Galactic disk

Tracers of chromospheric structure. I. CaII H$&$K emission distribution of 13000 F, G and K stars in SDSS DR7 spectroscopic sample

We present chromospheric activity index $Srm_{HK}$ measurements for over 13,000 F, G and K disk stars with high signal-to-noise ratio ($>$ 60) spectra in the Sloan Digital Sky Survey (SDSS) Data Release 7 (DR7) spectroscopic sample. A parameter $delta$S is defined as the difference between $Srm_{HK}$ and a `zero emission line fitted by several of the most inactive stars. The $Srm_{HK}$ indices of subgiant stars tend to be much lower than dwarfs, which provide a way to distinguish dwarfs and giants with relatively low resolution spectra. Cooler stars are generally more active and display a larger scatter than hotter stars. Stars associated with the thick disk are in general less active than those of the thin disk. The fraction of K dwarfs that are active drops with vertical distance from the Galactic plane. Metallicity affects $Srm_{HK}$ measurements differently among F, G and K dwarfs in this sample. Using the open clusters NGC 2420, M67 and NGC6791 as calibrations, ages of most field stars in this SDSS sample range from 3-8 Gyr.

New Diluted Ferromagnetic Semiconductor isostructural to 122 type iron pnictide superconductor with TC up to 180 K

Diluted magnetic semiconductors (DMS) have received much attention due to its potential applications to spintronics devices. A prototypical system (Ga,Mn)As has been widely studied since 1990s. The simultaneous spin and charge doping via hetero-valence (Ga3+,Mn2+) substitution, however, resulted in severely limited solubility without availability of bulk specimens. Previously we synthesized a new diluted ferromagnetic semiconductor of bulk Li(Zn,Mn)As with Tc up to 50K, where isovalent (Zn,Mn) spin doping was separated from charge control via Li concentrations. Here we report the synthesis of a new diluted ferromagnetic semiconductor (Ba1-xKx)(Zn1-yMny)2As2, isostructural to iron 122 system, where holes are doped via (Ba2+, K1+), while spins via (Zn2+,Mn2+) substitutions. Bulk samples with x=0.1-0.3 and y=0.05-0.15 exhibit ferromagnetic order with TC up to 180K, comparable to that of record high Tc for Ga(MnAs), significantly enhanced than Li(Zn,Mn)As. Moreover the (Ba,K)(Zn,Mn)2As2 shares the same 122 crystal structure with semiconducting BaZn2As2, antiferromagnetic BaMn2As2, and superconducting (Ba,K)Fe2As2, which makes them promising to the development of multilayer functional devices.

The doping dependence of superconductivity of (Ca1-xNax)Fe2As2

Single crystalline CaFe2As2 and (Ca1-xNax)Fe2As2 polycrystals (0 < x < 0.66) are synthesized and characterized using structural, magnetic, electronic transport, and heat capacity measurements. These measurements show that the structural/magnetic phase transition in CaFe2As2 at 165 K is monotonically suppressed by the Na doping and that superconductivity can be realized over a wide doping region. For 0.3 < x < 0.36, the magnetic susceptibilities indicate the possible coexistence of the spin density wave (SDW) and superconductivity. Superconducting phases corresponding to the Na doping level in (Ca1-xNax)Fe2As2 for nominal x = 0.36, 0.4, 0.5, 0.6, and 0.66, with Tc = 17 K, 19 K, 22 K, 33 K, and 33 K, respectively, are identified. The effects of the magnetic field on the superconductivity transitions for x = 0.66 samples with high upper critical fields Hc2 approx 103 T are studied, and a phase diagram of the SDW and superconductivity as a function of the doping level is thus presented.

Metallicity calibration for solar type stars based on red spectra

Based on high resolution and high signal-to-noise ratio (S/N) spectra analysis of 90 solar type stars, we have established several new metallicity calibrations in Teff range [5600, 6500] K based on red spectra with the wavelength range of 560-880 nm. The new metallicity calibrations are applied to determine the metallicity of solar analogs selected from SDSS spectra. There is a good consistent result with the adopted value presented in SDSS-DR7 and a small scatter of 0.26 dex for stars with S/N > 50 is obtained. This study provides a new reliable way to derive the metallicity for solar-like stars with low resolution spectra. In particular, our calibrations are useful for finding metal-rich stars, which are missing in SSPP.