The electronic Raman scattering in overdoped (Y,Ca)Ba2Cu3Oy was investigated with changing hole concentration in the superconducting state. It was found that the superconducting responses such as the pair-breaking peaks in the A1g and B1g spectra and
the anisotropy of the pair-breaking peak in XX and YY polarizations radically change at around the carrier doping p=0.19. Since both a- and c-axis resistivities strongly suggest the closing of pseudogap at p~0.18, the observed change at p=0.19 in superconducting Raman response is attributed to the electronic crossover due to the collapse of the pseudogap.
Electronic anisotropy was studied for overdoped (Y,Ca)Ba2Cu3O7-d with various doping levels (p). It was found that the pseudogap-like behavior in the resistivity disappear when p exceeds 0.17, independent of the oxygen deficiency. The anisotropy rati
o (g) estimated from upper critical fields showed a rapid decrease at around p = 0.18, approaching g = 3 for p > 0.20.