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Compared with direct-gap semiconductors, the valley degeneracy of silicon and germanium opens up new channels for spin relaxation that counteract the spin degeneracy of the inversion-symmetric system. Here the symmetries of the electron-phonon intera ction for silicon and germanium are identified and the resulting spin lifetimes are calculated. Room-temperature spin lifetimes of electrons in silicon are found to be comparable to those in gallium arsenide, however, the spin lifetimes in silicon or germanium can be tuned by reducing the valley degeneracy through strain or quantum confinement. The tunable range is limited to slightly over an order of magnitude by intravalley processes.
It is generally believed that a point defect in graphene gives rise to an impurity state at zero energy and causes a sharp peak in the local density of states near the defect site. We revisit the defect problem in graphene and find the general consen sus incorrect. By both analytic and numeric methods, we show that the contribution to the local density of states from the impurity state vanishes in the thermodynamic limit. Instead, the pronounced peak of the zero-bias anomaly is a power-law singularity $1/|E|$ from infinite resonant peaks in the low-energy regime induced by the defect. Our finding shows that the peak shall be viewed as a collective phenomenon rather than a single impurity state in previous studies.
The magnetic circular dichroism of III-V diluted magnetic semiconductors, calculated within a theoretical framework suitable for highly disordered materials, is shown to be dominated by optical transitions between the bulk bands and an impurity band formed from magnetic dopant states. The theoretical framework incorporates real-space Greens functions to properly incorporate spatial correlations in the disordered conduction band and valence band electronic structure, and includes extended and localized electronic states on an equal basis. Our findings reconcile unusual trends in the experimental magnetic circular dichroism in III-V DMSs with the antiferromagnetic p-d exchange interaction between a magnetic dopant spin and its host.
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