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We use the Space Telescope Imaging Spectrograph on board the Hubble Space Telescope to obtain new high-quality spectra covering the 1900 to 2360 Angstrom wavelength range for two metal-poor stars, HD 108317 and HD 128279. We derive abundances of Cu I I, Zn II, As I, Se I, Mo II, and Cd II, which have not been detected previously in either star. Abundances derived for Ge I, Te I, Os II, and Pt I confirm those derived from lines at longer wavelengths. We also derive upper limits from the non-detection of W II, Hg II, Pb II, and Bi I. The mean [As/Fe] ratio derived from these two stars and five others in the literature is unchanged over the metallicity range -2.8 < [Fe/H] < -0.6, <[As/Fe]> = +0.28 +/- 0.14 (std. dev. = 0.36 dex). The mean [Se/Fe] ratio derived from these two stars and six others in the literature is also constant, <[Se/Fe]> = +0.16 +/- 0.09 (std. dev. = 0.26 dex). The As and Se abundances are enhanced relative to a simple extrapolation of the iron-peak abundances to higher masses, suggesting that this mass region (75 < A < 82) may be the point at which a different nucleosynthetic mechanism begins to dominate the quasi-equilibrium alpha-rich freezeout of the iron peak. <[CuII/CuI]> = +0.56 +/- 0.23 in HD 108317 and HD 128279, and we infer that lines of Cu I may not be formed in local thermodynamic equilibrium in these stars. The [Zn/Fe], [Mo/Fe], [Cd/Fe], and [Os/Fe] ratios are also derived from neutral and ionized species, and each ratio pair agrees within the mutual uncertainties, which range from 0.15 to 0.52 dex.
Using near-ultraviolet spectra obtained with the Space Telescope Imaging Spectrograph onboard the Hubble Space Telescope, we detect neutral tellurium in three metal-poor stars enriched by products of r-process nucleosynthesis, BD+17 3248, HD 108317, and HD 128279. Tellurium (Te, Z=52) is found at the second r-process peak (A=130) associated with the N=82 neutron shell closure, and it has not been detected previously in Galactic halo stars. The derived tellurium abundances match the scaled solar system r-process distribution within the uncertainties, confirming the predicted second peak r-process residuals. These results suggest that tellurium is predominantly produced in the main component of the r-process, along with the rare earth elements.
We have derived new abundances of the rare-earth elements Pr, Dy, Tm, Yb, and Lu for the solar photosphere and for five very metal-poor, neutron-capture r-process-rich giant stars. The photospheric values for all five elements are in good agreement w ith meteoritic abundances. For the low metallicity sample, these abundances have been combined with new Ce abundances from a companion paper, and reconsideration of a few other elements in individual stars, to produce internally-consistent Ba, rare-earth, and Hf (56<= Z <= 72) element distributions. These have been used in a critical comparison between stellar and solar r-process abundance mixes.
Branching fraction measurements from Fourier transform spectra in conjunction with published radiative lifetimes are used to determine transition probabilities for 263 lines of neutral chromium. These laboratory values are employed to derive a new ph otospheric abundance for the Sun: log $epsilon$(Cr I)$_{odot}$ = 5.64$pm$0.01 ($sigma = 0.07$). These Cr I solar abundances do not exhibit any trends with line strength nor with excitation energy and there were no obvious indications of departures from LTE. In addition, oscillator strengths for singly-ionized chromium recently reported by the FERRUM Project are used to determine: log $epsilon$(Cr II)$_{odot}$ = 5.77$pm$0.03 ($sigma = 0.13$). Transition probability data are also applied to the spectra of three stars: HD 75732 (metal-rich dwarf), HD 140283 (metal-poor subgiant), and CS 22892-052 (metal-poor giant). In all of the selected stars, Cr I is found to be underabundant with respect to Cr II. The possible causes for this abundance discrepancy and apparent ionization imbalance are discussed.
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