The contact angle that a liquid drop makes on a soft substrate does not obey the classical Youngs relation, since the solid is deformed elastically by the action of the capillary forces. The finite elasticity of the solid also renders the contact ang
les different from that predicted by Neumanns law, which applies when the drop is floating on another liquid. Here we derive an elasto-capillary model for contact angles on a soft solid, by coupling a mean-field model for the molecular interactions to elasticity. We demonstrate that the limit of vanishing elastic modulus yields Neumanns law or a slight variation thereof, depending on the force transmission in the solid surface layer. The change in contact angle from the rigid limit (Young) to the soft limit (Neumann) appears when the length scale defined by the ratio of surface tension to elastic modulus $gamma/E$ reaches a few molecular sizes.
A solid object can be coated by a nonwetting liquid since a receding contact line cannot exceed a critical speed. We theoretically investigate this forced wetting transition for axisymmetric menisci on fibers of varying radii. First, we use a matched
asymptotic expansion and derive the maximum speed of dewetting. For all radii we find the maximum speed occurs at vanishing apparent contact angle. To further investigate the transition we numerically determine the bifurcation diagram for steady menisci. It is found that the meniscus profiles on thick fibers are smooth, even when there is a film deposited between the bath and the contact line, while profiles on thin fibers exhibit strong oscillations. We discuss how this could lead to different experimental scenarios of film deposition.
The entrainment of air by advancing contact lines is studied by plunging a solid plate into a very viscous liquid. Above a threshold velocity, we observe the formation of an extended air film, typically 10 microns thick, which subsequently decays int
o air bubbles. Exploring a large range of viscous liquids, we find an unexpectedly weak dependence of entrainment speed on liquid viscosity, pointing towards a crucial role of the flow inside the air film. This induces a striking asymmetry between wetting and dewetting: while the breakup of the air film strongly resembles the dewetting of a liquid film, the wetting speeds are larger by orders of magnitude.
For packings of hard but not perfectly rigid particles, the length scales that govern the packing geometry and the contact forces are well separated. This separation of length scales is explored in the force network ensemble, where one studies the sp
ace of allowed force configurations for a given, frozen contact geometry. Here we review results of this approach, which yields nontrivial predictions for the effect of packing dimension and anisotropy on the contact force distribution $P(f)$, the response to overall shear and point forcing, all of which can be studied in great numerical detail. Moreover, there are emerging analytical approaches that very effectively capture, for example, the form of force distributions.
