Co-doped BaFe2As2 has been previously shown to have an unusually significant improvement of Tc (up to 2 K, or almost 10%) with annealing 1-2 weeks at 700 or 800 C, where such annealing conditions are insufficient to allow significant atomic diffusion
. While confirming similar behavior in optimally Co-doped SrFe2As2 samples, the influence on Tc of strain induced by grinding to ~50 micron sized particles, followed by pressing the powder into a pellet using 10 kbar pressure, was found to increase the annealed transition width of 1.5 K by approximately a factor of ten. Also, the bulk discontinuity in the specific heat at Tc, deltaC, on the same pellet sample was completely suppressed by grinding. This evidence for a strong sensitivity of superconductivity to strain was used to optimize single crystal growth of Co-doped BaFe2As2. This strong dependence (both positive via annealing and negative via grinding) of superconductivity on strain in these two iron based 122 structure superconductors is compared to the unconventional heavy Fermion superconductor UPt3, where grinding is known to completely suppress superconductivity, and to recent reports of strong sensitivity of Tc to damage induced by electron-irradiation-induced point defects in other 122 structure iron-based superconductors, Ba(Fe0.76Ru0.24)2As2 and Ba1-xKxFe2As2. Both the electron irradiation and the introduction of strain by grinding are believed to only introduce non-magnetic defects, and argue for unconventional superconducting pairing.
The pairing symmetry in the iron-based superconductor Ba1-xKxFe2As2 may change from nodeless s-wave near x~0.4 and Tc>30 K, to nodal (either d-wave or s-wave) at x=1 and Tc<4 K. Theoretical interest has been focused on this possibility, where in the
transition region both order parameters would be present and time reversal symmetry would be broken. We report specific heat in magnetic fields down to 0.4 K of three single crystals, free of low temperature magnetic anomalies, of heavily overdoped Ba1-xKxFe2As2, x= 0.91, 0.88, and 0.81, Tc(mid) ~ 5.6, 7.2 and 13 K and Hc2 ~ 4.5, 6, and 20 T respectively. The data can be analyzed in a two gap scenario, Delta2/Delta1 ~ 4, with the field dependence of gamma (=C/T as T->0) showing an S-shape vs H, with the suppression of the lower gap by 1 T and gamma ~ H**1/2 overall. Although such a non-linear gamma vs H is consistent with deep minima or nodes in the gap, it is not clear evidence for one, or both, of the gaps being nodal. Following the established analysis of the specific heat of d-wave cuprate superconductors containing line nodes, we present the specific heat/H**1/2 vs T/H**1/2 of these Ba1-xKxFe2As2 samples which all, due to the absence of magnetic impurities, convincingly show the scaling for line node behavior for the larger gap. There is however no clear observation of the nodal behavior C ~ alpha*T**2 in zero field at low temperatures, with alpha ~ 2 mJ/molK**3 being consistent with the data. This, with the scaling, leaves the possibility of extreme anisotropy in a nodeless larger gap, Delta2, such that the scaling works for fields above 0.25 to 0.5 T (0.2 to 0.4 K in temperature units), where this an estimate for the size of the deep minima in the Delta2 ~ 20-25 K gap. Thus, the change from nodeless to nodal gaps in Ba1-xKxFe2As2 may be closer to the KFe2As2 endpoint than x=0.91.
The specific heat of single crystal hole-doped Ca0.33Na0.67Fe2As2, Tc(onset)=33.7 K, was measured from 0.4 to 40 K. The discontinuity in the specific heat at Tc, deltaC, divided by Tc is 105 +- 5 mJ/molK2, consistent with values found previously for
hole-doped Ba0.6K0.4Fe2As2 and somewhat above the general trend for deltaC/Tc vs Tc for the iron based superconductors established by Budko, Ni and Canfield. The usefulness of measured valued of deltaC/Tc as an important metric for the quality of samples is discussed.
Low temperature specific heat, C, in magnetic fields up to Hc2 is reported for underdoped Ba(Fe0.955Co0.045)2As2 (Tc=8 K) and for three overdoped samples Ba(Fe1-xCox)2As2 (x=0.103, 0.13, and 0.15, Tc=17.2, 16.5, and 11.7 K respectively). Previous mea
surements of thermal conductivity (as a function of temperature and field) and penetration depth on comparable composition samples gave some disagreement as to whether there was fully gapped/nodal behavior in the under-/overdoped materials respectively. The present work shows that the measured behavior of the specific heat gamma (proportional to C/T as T->0, i. e. a measure of the electronic density of states at the Fermi energy) as a function of field approximately obeys gamma proportional to H**(0.5 +- 0.1), similar to the Volovik effect for nodal superconductors, for both the underdoped and the most overdoped Co samples. However, for the two overdoped compositions x=0.103 and 0.13, the low field (H < 10 T) data show a Volovik-like behavior of gamma proportional to H**(0.3-0.4), followed by an inflection point, followed at higher fields by gamma proportional to H**1. We argue that within the 2-band theory of superconductivity, an inflection point may occur if the interband coupling is dominant.
We investigate on-site Coulomb interaction energy between two 3p holes U(Ni 3p) of ultrathin NiO films on Ag(001) by both x-ray photoelectron spectroscopy and Auger electron spectroscopy. As the film becomes thin, U(Ni 3p) monotonically decreases, an
d the difference of U(Ni 3p) for 1 monolayer (ML) film from that of bulk-like thick film delta U(Ni 3p) reaches ~ -2.2 eV. The observed delta U(Ni 3p) for 1 ML film is well reproduced by the differences of both the image potential and polarization energies between 1 ML film and the bulk-like thick film. Hence, the present results provide an evidence for the picture originally proposed by Duffy et al. [J. Phys. C: Solid State Phys., 16, 4087 (1983)] and Altieri et al. [Phys. Rev. B 59, R2517 (1999)]
We investigate the unusual magnetic properties of nearly-critical, weakly-itinerant ferromagnets with general formula UTX, where T=Rh,Co and X=Ge,Si. As a unique feature about these systems, we show that changes in the V_{df} hybridization control th
eir proximity to a ferromagnetic instability, and determine the evolution of: the ground state magnetization, M_0, the Curie Temperature, T_C, the density of states at the Fermi level, N(E_F), the T^2 resistivity coefficient, A, and the specific heat coefficient, gamma. The universal aspect of our findings comes from the dependence on only two parameters: the T_d bandwidth, W_d, and the distance between T_d and U_f band centers, C_{T_d}-C_{U_f}.
We report specific heat measurements on the Fe-based superconductor BaFe2(As0.7P0.3)2, a material on which previous penetration depth, NMR, and thermal conductivity measurements have observed a high density of low-energy excitations, which have been
interpreted in terms of order parameter nodes. Within the resolution of our measurements, the low temperature limiting C/T is found to be linear in field, i.e. we find no evidence for a Volovik effect associated with nodal quasiparticles in either the clean or dirty limit. We discuss possible reasons for this apparent contradiction.
We present a combined experimental and theoretical study of the effects of pressure on T_c of the hexagonal layered superconductors nH-CaAlSi (n = 1, 5, 6), where nH labels the different stacking variants that were recently discovered. Experimentally
, the pressure dependence of T_c has been investigated by measuring the magnetic susceptibility of single crystals up to 10 kbar. In contrast to previous results on polycrystalline samples, single crystals with different stacking sequences display different pressure dependences of T_c. 1H-CaAlSi shows a decrease of T_c with pressure, whereas 5H and 6H-CaAlSi exhibit an increase of T_c with pressure. Ab-initio calculations for 1H, 5H and 6H -CaAlSi reveal that an ultrasoft phonon branch associated to out-of-plane vibrations of the Al-Si layers softens with pressure, leading to a structural instability at high pressures. For 1H-CaAlSi the softening is not sufficient to cause an increase of T_c, which is consistent with the present experiments, but adverse to previous reports. For 5H and 6H the softening provides the mechanism to understand the observed increase of T_c with pressure. Calculations for hypothetical 2H and 3H stacking variants reveal qualitative and quantitative differences.
