HCl and HF are expected to be the main reservoirs of fluorine and chlorine wherever hydrogen is predominantly molecular. They are found to be strongly depleted in dense molecular clouds, suggesting freeze-out onto grains in such cold environments. We
can then expect that HCl and HF were also the major carriers of Cl and F in the gas and icy phases of the outer solar nebula, and were incorporated into comets. We aimed to measure the HCl and HF abundances in cometary ices as they can provide insights on the halogen chemistry in the early solar nebula. We searched for the J(1-0) lines of HCl and HF at 626 and 1232 GHz, respectively, using the HIFI instrument on board the Herschel Space Observatory. HCl was searched for in comets 103P/Hartley 2 and C/2009 P1 (Garradd), whereas observations of HF were conducted in comet C/2009 P1. In addition, observations of H$_2$O and H$_2^{18}$O lines were performed in C/2009 P1 to measure the H$_2$O production rate. Three lines of CH$_3$OH were serendipitously observed in the HCl receiver setting. HCl is not detected, whereas a marginal (3.6-$sigma$) detection of HF is obtained. The upper limits for the HCl abundance relative to water are 0.011% and 0.022%, for 103P and C/2009 P1, respectively, showing that HCl is depleted with respect to the solar Cl/O abundance by a factor more than 6$^{+6}_{-3}$ in 103P, where the error is related to the uncertainty in the chlorine solar abundance. The marginal HF detection obtained in C/2009 P1 corresponds to an HF abundance relative to water of (1.8$pm$0.5) $times$ 10$^{-4}$, which is approximately consistent with a solar photospheric F/O abundance. The observed depletion of HCl suggests that HCl was not the main reservoir of chlorine in the regions of the solar nebula where these comets formed. HF was possibly the main fluorine compound in the gas phase of the outer solar nebula.
The high spectral resolution and sensitivity of Herschel/HIFI allows for the detection of multiple rotational water lines and accurate determinations of water production rates in comets. In this letter we present HIFI observations of the fundamental
110-101 (557 GHz) ortho and 111-000 (1113 GHz) para rotational transitions of water in comet 81P/Wild 2 acquired in February 2010. We mapped the extent of the water line emission with five point scans. Line profiles are computed using excitation models which include excitation by collisions with electrons and neutrals and solar infrared radiation. We derive a mean water production rate of $1.0 times 10^{28}$ molecules s$^{-1}$ at a heliocentric distance of 1.61 AU about 20 days before perihelion, in agreement with production rates measured from the ground using observations of the 18-cm OH lines. Furthermore, we constrain the electron density profile and gas kinetic temperature, and estimate the coma expansion velocity by fitting the water line shapes.
High-resolution far-infrared and sub-millimetre spectroscopy of water lines is an important tool to understand the physical and chemical properties of cometary atmospheres. We present observations of several rotational ortho- and para-water transitio
ns in comet C/2008 Q3 (Garradd) performed with HIFI on Herschel. These observations have provided the first detection of the 2_{12}-1_{01} (1669 GHz) ortho and 1_{11}-0_{00} (1113 GHz) para transitions of water in a cometary spectrum. In addition, the ground-state transition 1_{10}-1_{01} at 557 GHz is detected and mapped. By detecting several water lines quasi-simultaneously and mapping their emission we can constrain the excitation parameters in the coma. Synthetic line profiles are computed using excitation models which include excitation by collisions, solar infrared radiation, and radiation trapping. We obtain the gas kinetic temperature, constrain the electron density profile, and estimate the coma expansion velocity by analyzing the map and line shapes. We derive water production rates of 1.7-2.8 x 10^{28} s^{-1} over the range r_h = 1.83-1.85 AU.
A fundamental question in cometary science is whether the different dynamical classes of comets have different chemical compositions, which would reflect different initial conditions. From the ground or Earth orbit, radio and infrared spectroscopic o
bservations of a now significant sample of comets indeed reveal deep differences in the relative abundances of cometary ices. However, no obvious correlation with dynamical classes is found. Further results come, or are expected, from space exploration. Such investigations, by nature limited to a small number of objects, are unfortunately focussed on short-period comets (mainly Jupiter-family). But these in situ studies provide ground truth for remote sensing. We discuss the chemical differences in comets from our database of spectroscopic radio observations, which has been recently enriched by several Jupiter-family and Halley-type comets.
Radio observations from decimetric to submillimetric wavelengths are now a basic tool for the investigation of comets. Spectroscopic observations allow us i) to monitor the gas production rate of the comets, by directly observing the water molecule,
or by observing secondary products (e.g., the OH radical) or minor species (e.g., HCN); ii) to investigate the chemical composition of comets; iii) to probe the physical conditions of cometary atmospheres: kinetic temperature and expansion velocity. Continuum observations probe large-size dust particles and (for the largest objects) cometary nuclei. Comets are classified from their orbital characteristics into two separate classes: i) nearly-isotropic, mainly long-period comets and ii) ecliptic, short-period comets, the so-called Jupiter-family comets. These two classes apparently come from two different reservoirs, respectively the Oort cloud and the trans-Neptunian scattered disc. Due to their different history and - possibly - their different origin, they may have different chemical and physical properties that are worth being investigated. The present article reviews the contribution of radio observations to our knowledge of the Jupiter-family comets (JFCs). The difficulty of such a study is the commonly low gas and dust productions of these comets. Long-period, nearly-isotropic comets from the Oort cloud are better known from Earth-based observations. On the other hand, Jupiter-family comets are more easily accessed by space missions. However, unique opportunities to observe Jupiter-family comets are offered when these objects come by chance close to the Earth. About a dozen JFCs were successfully observed by radio techniques up to now. No obvious evidence for different properties between JFCs and other families of comets is found.
