Context: We have analysed Herschel-PACS spectra of 32 circumstellar disks around Herbig Ae/Be and T-Tauri stars obtained within the Herschel key programme DIGIT. In this paper we focus on the 69mu emission band of the crystalline silicate forsterite.
Aims: This work provides an overview of the 69mu forsterite bands in the DIGIT sample. We aim to derive the temperature and composition of the forsterite grains. With this information, constraints can be placed on the spatial distribution of the forsterite in the disk and its formation history. Methods: Position and shape of the 69mu band are used to derive the temperature and composition of the dust by comparison to laboratory spectra of that band. We combine our data with existing Spitzer IRS spectra to compare the presence and strength of the 69mu band to the forsterite bands at shorter wavelengths. Results: A total of 32 sources have been observed, 8 of them show a 69mu emission band that can be attributed to forsterite. With the exception of the T-Tauri star AS205, all of the detections are for disks associated with Herbig Ae/Be stars. Most of the forsterite grains that give rise to the 69mu bands are warm (~100-200 K) and iron-poor (less than ~2% iron). Only AB-Aur requires approximately 3-4% of iron. Conclusions: Our findings support the hypothesis that the forsterite grains form through an equilibrium condensation process at high temperatures. The connection between the strength of the 69 and 33mu bands shows that at least part of the emission in these bands originates from the same dust grains. Further, any model that explains the PACS and the Spitzer IRS observations must take the effects of a wavelength dependent optical depth into account. We find indications of a correlation of the detection rate of the 69mu band with the spectral type of the host stars. However, our sample is too small to obtain a definitive result.
Aims. In this paper we study the Spitzer and TIMMI2 infrared spectra of post-AGB disc sources, both in the Galaxy and the LMC. Using the observed infrared spectra we determine the mineralogy and dust parameters of the discs, and look for possible dif
ferences between the Galactic and extragalactic sources. Methods. Modelling the full spectral range observed allows us to determine the dust species present in the disc and different physical parameters such as grain sizes, dust abundance ratios, and the dust and continuum temperatures. Results. We find that all the discs are dominated by emission features of crystalline and amorphous silicate dust. Only a few sample sources show features due to CO2 gas or carbonaceous molecules such as PAHs and C60 fullerenes. Our analysis shows that dust grain processing in these discs is strong, resulting in large average grain sizes and a very high crystallinity fraction. However, we do not find any correlations between the derived dust parameters and properties of the central source. There also does not seem to be a noticeable difference between the mineralogy of the Galactic and LMC sources. Even though the observed spectra are very similar to those of protoplanetary discs around young stars, showing similar mineralogy and strong grain processing, we do find evidence for differences in the physical and chemical processes of the dust processing.
We present far-infrared spectroscopic observations, taken with the Photodetector Array Camera and Spectrometer (PACS) on the Herschel Space Observatory, of the protoplanetary disk around the pre-main-sequence star HD 100546. These observations are th
e first within the DIGIT Herschel key program, which aims to follow the evolution of dust, ice, and gas from young stellar objects still embedded in their parental molecular cloud core, through the final pre-main-sequence phases when the circumstellar disks are dissipated. Our aim is to improve the constraints on temperature and chemical composition of the crystalline olivines in the disk of HD 100546 and to give an inventory of the gas lines present in its far-infrared spectrum. The 69 mum feature is analyzed in terms of position and shape to derive the dust temperature and composition. Furthermore, we detected 32 emission lines from five gaseous species and measured their line fluxes. The 69 mum emission comes either from dust grains with ~70 K at radii larger than 50 AU, as suggested by blackbody fitting, or it arises from ~200 K dust at ~13 AU, close to the midplane, as supported by radiative transfer models. We also conclude that the forsterite crystals have few defects and contain at most a few percent iron by mass. Forbidden line emission from [CII] at 157 mum and [OI] at 63 and 145 mum, most likely due to photodissociation by stellar photons, is detected. Furthermore, five H2O and several OH lines are detected. We also found high-J rotational transition lines of CO, with rotational temperatures of ~300 K for the transitions up to J=22-21 and T~800 K for higher transitions.
Context. Icy dust grains play an important role in the formation of complex inter- and circumstellar molecules. Observational studies show that polycyclic aromatic hydrocarbons (PAHs) are abundantly present in the ISM in the gas phase. It is likely t
hat these non-volatile species freeze out onto dust grains as well and participate in the astrochemical solid-state network, but experimental PAH ice studies are largely lacking. Methods. Near UV/VIS spectroscopy is used to track the in situ VUV driven photochemistry of pyrene containing ices at temperatures ranging from 10 to 125 K. Results. The main photoproducts of VUV photolyzed pyrene ices are spectroscopically identified and their band positions are listed for two host ices, water and CO. Pyrene ionisation is found to be most efficient in water ices at low temperatures. The reaction products, triplet pyrene and the 1-hydro-1-pyrenyl radical are most efficiently formed in higher temperature water ices and in low temperature CO ice. Formation routes and band strength information of the identified species are discussed. Additionally, the oscillator strengths of Py, Py^+ and PyH are derived and a quantitative kinetic analysis is performed by fitting a chemical reaction network to the experimental data. Conclusions. Pyrene is efficiently ionised in water ice at temperatures below 50 K. Hydrogenation reactions dominate the chemistry in low temperature CO ice with trace amounts of water. The results are put in an astrophysical context by determining the importance of PAH ionisation in a molecular cloud. The photoprocessing of a sample PAH in ice described in this manuscript indicates that PAH photoprocessing in the solid state should also be taken into account in astrochemical models.
Herbig Ae/Be stars are a class of young pre-main sequence stellar objects of intermediate mass and are known to have varying amounts of natal cloud material still present in their direct vicinity. We characterise the IR emission bands, due to fluores
cence by PAH molecules, in the spectra of Herbig Ae/Be stars and link observed variations to spatial aspects of the mid-IR emission. We analysed two PAH dominated spectra from a sample of 15 Herbig Ae/Be stars observed with Spitzer and derive profiles of the major PAH bands. The shape and the measured band characteristics show pronounced variations between the two Spitzer spectra. Those variations parallel those found between three ISO spectra of other, well-studied, Herbig Ae/Be stars. The derived profiles are compared to those from a broad sample of sources. The Spitzer and ISO spectra exhibit characteristics commonly interpreted respectively as interstellar matter-like (ISM), non-ISM-like, or a combination of the two. We argue that the PAH emission detected from the sources exhibiting a combination of ISM-like and non-ISM-like characteristics indicates the presence of two dissimilar, spatially separated, PAH families. As the shape of the individual PAH band profiles reflects the composition of the PAH molecules involved, this demonstrates that PAHs in subsequent, evolutionary linked stages of star formation are different from those in the general ISM, implying active chemistry. None of the detected PAH emission can be associated with the (unresolved) disk and is thus associated with the circumstellar cloud. This implies that chemical changes may already occur in the natal cloud and not necessarily in the disk.
