Methanol is observed in a wide range of astrophysical sources throughout the universe, and comprehensive databases of the millimeter and THz spectra of CH3OH and its principal isotopologues represent important tools for the astronomical community. A
previous combined analysis of microwave and millimeter wave spectra of 13CH3OH together with Fourier transform far-infrared spectra was limited to the first two torsional states, v_t = 0 and 1, for J values up to 20. The limits on frequency and quantum number coverage have recently been extended by new millimeter and THz measurements on several different spectrometers in the Cologne laboratory in the frequency windows 34-70 GHz, 75-120 GHz, 240-340 GHz, 360-450 GHz and 1.12-1.50 THz. With the new data, the global treatment has now been expanded to include the first three torsional states for J values up to 30. The current 13CH3OH data set contains about 2,300 microwave, millimeter-wave, sub-millimeter and THz lines and about 17,100 Fourier-transform far-infrared lines, representing the most recent available information in the quantum number ranges J </= 30, K </= 13 and v_t </= 2. The transitions have been successfully fitted to within the assigned measurement uncertainties of +/-50 kHz for most of the frequency-measured (i.e. MW, MMW, Sub-MMW, THz) lines and +/-6 MHz for the FIR lines. A convergent global fit was achieved using 103 adjustable parameters to reach an overall weighted standard deviation of 1.37. Our new C-13 methanol database is improved substantially compared to the existing one (Li-Hong Xu, F.J. Lovas, J. Phys. Chem. Ref. Data 26 (1997) 17-156), and will be available in the Cologne Database for Molecular Spectroscopy, CDMS (http://www.astro.unikoeln.de/cdms/). (Abbreviated)
Torsion-rotation transitions in molecules exhibiting hindered internal rotation possess enhanced sensitivities to a variation of the proton-to-electron mass ratio. This enhancement occurs due to a cancellation of energies associated with the torsiona
l and rotational degrees of freedom of the molecule. This effect occurs generally in every internal rotor molecule, but is exceptionally large in methanol. In this paper we calculate the sensitivity coefficients of methyl mercaptan, the thiol analogue of methanol. The obtained sensitivity coefficients in this molecule range from $K_mu=-14.8$ to $+12.2$ for transitions with a lower-level excitation energy below 10,cm$^{-1}$.
Recently, methanol was identified as a sensitive target system to probe variations of the proton-to-electron mass ratio $mu$ [Jansen emph{et al.} Phys. Rev. Lett. textbf{106}, 100801 (2011)]. The high sensitivity of methanol originates from the inter
play between overall rotation and hindered internal rotation of the molecule -- i.e. transitions that convert internal rotation energy into overall rotation energy, or vice versa, give rise to an enhancement of the sensitivity coefficient, $K_{mu}$. As internal rotation is a common phenomenon in polyatomic molecules, it is likely that other molecules display similar or even larger effects. In this paper we generalize the concepts that form the foundation of the high sensitivity in methanol and use this to construct an approximate model which allows to estimate the sensitivities of transitions in internal rotor molecules with $C_{3v}$ symmetry, without performing a full calculation of energy levels. We find that a reliable estimate of transition sensitivities can be obtained from the three rotational constants ($A$, $B$, and $C$) and three torsional constants ($F$, $V_3$ and $rho$). This model is verified by comparing obtained sensitivities for methanol, acetaldehyde, acetamide, methyl formate and acetic acid with a full analysis of the molecular Hamiltonian. From the molecules considered, methanol appears to be the most suitable candidate for laboratory and cosmological tests searching for a possible variation of $mu$.
Room temperature ferromagnetism was observed in n-type Fe-doped In2O3 thin films deposited on c-cut sapphire substrates by pulsed laser deposition. Structure, magnetism, composition, and transport studies indicated that Fe occupied the In sites of th
e In2O3 lattice rather than formed any metallic Fe or other magnetic impurity phases. Magnetic moments of films were proved to be intrinsic and showed to have a strong dependence on the carrier densities which depended on the Fe concentration and its valance state as well as oxygen pressure.
